Heteroepitaxy of Hexagonal ZnS Thin Films Directly on Si (111)
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概要
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Epitaxial Wurtzite ZnS (W-ZnS) films were grown directly on Si (111) at temperatures as high as 800°C by pulsed laser deposition. A detailed deconvolution method was used to discriminate the ZnS reflection from superimposed peaks overlapped by both ZnS and Si peaks in X-ray measurement. From the peak deconvolution, the rocking full width at half maximum and lattice constant of the ZnS film were determined to be 0.28° and 6.26 Å, respectively. A tilt between W-ZnS and Si was observed and the tilt angle decreased with increasing growth temperature. The W-ZnS (0001) film on Si (111) showed the epitaxial relationship of Si [220]//ZnS[$10\bar{1}5$]. An X-ray diffraction scan along the L direction in reciprocal space and a high-resolution transmission electron microscopy image revealed that the W-ZnS film partially had stacking fault domains in the hexagonal phase. Free excitonic emission from the W-ZnS film was observed at 4 K.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2003-11-15
著者
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Koinuma Hideomi
Materials And Structures Labolatory Tokyo Institute Of Technology
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ONUMA Takeyohi
Institute of Applied Physics and Graduate School of Pure and Applied Sciences, University of Tsukuba
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Chichibu Shigefusa
Institute Of Applied Physics And 21st Century Center-of-excellence Office University Of Tsukuba
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Chikyow Toyohiro
National Inst. Materials Sci. Ibaraki Jpn
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Yoo Young-zo
National Institute For Materials Science
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Kawasaki Masashi
Institute For Chemical Research Kyoto University
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Yoo Young-Zo
National Institute for Materials Science, Nanomaterials Assembly Group, 1-2-1, Sengen Tsukuba 305-0044, Japan
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Chikyow Toyohiro
National Institute for Materials Science, Nanomaterials Assembly Group, 1-2-1, Sengen Tsukuba 305-0044, Japan
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Chichibu Shigefusa
Institute of Applied Physics and Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8573, Japan
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Onuma Takeyohi
Institute of Applied Physics and Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8573, Japan
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