A Synthesis of (±)-Dihydrodeoxyepiallocernuine by Application of a Facile Hofmann-Loeffler Type of Photocyclization
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概要
- 論文の詳細を見る
Pelletierine which was established to be a precursor in the biosynthesis of cernuine (1), was converted into the quinolizidine (22), whose N-chloro derivative (27) was irradiated with 300 W high pressure mercury lamp in ether in the absence of any strong acid to readily afford the entitled compound (3) as the free base with no base treatment. The present photocyclization is thus different from the known Hofmann-Loeffler reaction in several respects, which are demonstrated for discussion.
- 公益社団法人日本薬学会の論文
- 1976-07-25
著者
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木村 正幸
Faculty Of Pharmaceutical Sciences Hokkaido University
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大石 武
Faculty Of Engineering Yokohama National University:(present Address)meiji College Of Pharmacy
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伴 義雄
東邦大・薬
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伴 義雄
Faculty Of Pharmaceutical Sciences Hokkaido University
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大石 武
北大・薬:(現)理化学研究所
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