ELECTRONIC EFFECTS ON THE REGIOSELECTIVITY IN THE REACTIONS OF THIOALLYLIC ANIONS WITH CARBONYL COMPOUNDS
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概要
- 論文の詳細を見る
In the reactions of lithium salts of allylic N, N-dimethyldithiocarbamates with p-substituted aromatic aldehydes and ketones, the α-selectivity increases as the substituent of the phenyl ring becomes more electron-attractive. The regioselectivity also depends upon the substitution pattern of the allylic moiety. The Hard and Soft Acid and Base (HSAB) approach was used to rationalize the results.
- 社団法人日本薬学会の論文
- 1982-10-25
著者
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大石 武
Faculty Of Engineering Yokohama National University:(present Address)meiji College Of Pharmacy
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馬場 英夫
The Institute Of Physical And Chemical Research (riken)
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林 俊雄
The Institute of Physical and Chemical Research (Riken)
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大石 武
The Institute of Physical and Chemical Research (Riken)
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