Synthetic Study of Siccanin, an Antifungal Antibiotic. III. Some Diels-Alder Adducts of 2-Methoxy-5-methoxycarbonylbenzoquinone
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概要
- 論文の詳細を見る
The Diels-Alder reaction of 2-methoxy-5-methoxycarbonylbenzoquinone (6) with various 1-substituted isoprenes (5a-d) was studied and the 8β-substituted cis-tetrahydronapthoquinone-8aα-carboxylates (19a-d) were obtained and characterized. Some of the latter compounds are important intermediates for synthesis of the A and B rings of siccanin (3), an antifungal antibiotic.
- 社団法人日本薬学会の論文
- 1973-03-25
著者
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大木 英二
Central Research Laboratories, Sankyo Co., Ltd.
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老田 貞夫
Central Research Laboratories, Sankyo Co., Ltd.
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大橋 芳彦
Central Research Laboratories, Sankyo Co., Ltd.
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大橋 芳彦
Central Research Laboratories Sankyo Co. Ltd.
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大木 英二
Research Laboratory Zenyaku Kogyo Co. Ltd.
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大木 英二
Central Research Laboratories Sankyo Co. Ltd.
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老田 貞夫
Medicinal Chemistry Research Laboratories Sankyo Co. Ltd.
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