Deoxysugar Synthesis. II. Deoxygenations of Methyl 2,6-Dibenzyloxy-carbonylamino-2,6-dideoxy-α-D-glucopyranoside
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概要
- 論文の詳細を見る
The 3-p-toluenesulfonate (4) of methyl 2,6-dibenzyloxycarbonylamino-2,6-dideoxy-α-D-glucopyranoside was treated with sodium borohydride in dimethyl sulfoxide, giving 3-deoxy-and 4-deoxy-α-D-ribo-hexopyranosides (10 and 11) in a ratio of 1 : 5. On the other hand, analogous treatment of the 4-p-toluenesulfonate (5) afforded the allo-3,4-epoxide (19). Further, related study was described.
- 社団法人日本薬学会の論文
- 1976-04-25
著者
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大木 英二
Central Research Laboratories, Sankyo Co., Ltd.
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佐伯 博道
Central Research Laboratories, Sankyo Co., Ltd.
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島田 芳和
Central Research Laboratories, Sankyo Co., Ltd.
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大木 英二
Research Laboratory Zenyaku Kogyo Co. Ltd.
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大木 英二
Central Research Laboratories Sankyo Co. Ltd.
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武田 憲子
Central Research Laboratories, Sankyo Co., Ltd.
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武田 憲子
Medical Chemistry Research Laboratories Sankyo Co. Ltd.
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島田 芳和
Central Research Laboratories Sankyo Co. Ltd.
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佐伯 博道
Central Research Laboratories Sankyo Co. Ltd.
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