Syntheses of Tricyclic Amines from Azabicyclic Compounds through Carbenes
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概要
- 論文の詳細を見る
It was found that the insertion reaction of a carbene produced at bridged carbon (C_9) of 3-methyl-3-azabicyclo [3. 3. 1] nonane proceeded exclusively into the opposite side to N-methyl group to yield 3-methyl-3-azatricyclo [6. 1. 0. 0^<5,9>] nonane (III), while that of a carbene at bridged carbon (C_8) of 3-methyl-3-azabicyclo [3. 2. 1] octane was to the same side of N-methyl group to give 2-methyl-2-azatricyclo [5. 1. 0. 0^<4,8>] octane (XV).
- 公益社団法人日本薬学会の論文
- 1968-04-25
著者
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大木 英二
Central Research Laboratories, Sankyo Co., Ltd.
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老田 貞夫
Central Research Laboratories, Sankyo Co., Ltd.
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老田 貞夫
Medicinal Chemistry Research Laboratories Sankyo Co. Ltd.
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