Hard Acid and Soft Nucleophile System. VII. A Convenient Reduction of Functionalized Polyarenes to Parent Polyarenes

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概要

• 論文の詳細を見る

• Oxygen functions and halogens at the peri-carbon atom in polyarenes were reductively removed with the AlCl_3-EtSH reagent system to afford the parent polyarenes in high yield. The reaction consists of two steps of reactions involving displacement of a functionality with an alkylthio group followed by reductive removal of the introduced alkylthio moiety. A radical cation induced mechanism for the latter process is proposed on the basis of several observations.

• 公益社団法人日本薬学会の論文
• 1983-12-25

著者

• 野出 学

  Kyoto Pharmaceutical University

• 野出 学

  Institute For Chemical Research Kyoto University

• 藤田 榮一

  Osaka University of Pharmaceutical Sciences

• 西出 喜代治

  京都薬科大学薬品製造学教室 創薬科学フロンティア研究センター

• 太田 敬一郎

  Institute For Chemical Research Kyoto University

• 冨士 薫

  Institute For Chemical Research Kyoto University

• 川端 猛夫

  京都大学化学研究所

• 藤田 栄一

  京都大学化学研究所

• 藤田 栄一

  Osaka University Of Pharmaceutical Sciences

• 藤田 栄一

  Institute for Chemical Research, Kyoto University

• 川端 猛夫

  Institute for Chemical Research, Kyoto University

• 西出 喜代治

  Institute for Chemical Research, Kyoto University

• 太田 啓一郎

  Institute for Chemical Research, Kyoto University

• 渡辺 宏二

  Institute for Chemical Research, Kyoto University

• 藤田 栄一

  Institute For Chemical Research Kyoto University

• 川端 猛夫

  京大化研

• 渡辺 宏二

  Institute For Chemical Research Kyoto University

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