各種結合の選択的開裂に有用なハード酸-ソフト求核剤組合せ系新反応剤の開発研究
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概要
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A chemical bond has the hard-soft dissymmetry as well as the charge dissymmetry. Thus, a combination system of a hard acid and a soft nucleophile is able to cleave the bond which consists of a hard base and a soft acid. Recently, the author has developed a number of combination systems for the cleavage reactions of various bonds. This article describes the cleavage reaction of C-O, C-halogen, C-NO_2,C-S, and C=C bonds with a combination system consisting of a hard Lewis acid and a soft nucleophile.
- 公益社団法人日本薬学会の論文
- 1986-01-25
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- 各種結合の選択的開裂に有用なハード酸-ソフト求核剤組合せ系新反応剤の開発研究
- ハード酸・ソフト求核剤組合せ系のデザイン : 結合開裂反応への応用