A Chiral Synthesis of a Unique Secodehydroabietane from Tall Oil
スポンサーリンク
概要
- 論文の詳細を見る
A total synthesis of naturally occurring (+)-9,10-secoabieta-8,11,13-trien-18,10-olide (1) has been achieved from a chiral building block, (R)-2-methyl-2-(2-E-nitrovinyl)-5-pentanolide (3).
- 公益社団法人日本薬学会の論文
- 1991-01-25
著者
-
野出 学
Kyoto Pharmaceutical University
-
野出 学
Institute For Chemical Research Kyoto University
-
冨士 薫
Institute For Chemical Research Kyoto University
-
冨士 薫
京都大学化学研究所
-
〓 小江
Institute For Chemical Research Kyoto University
-
〓 尚珍
Institute for Chemical Research, Kyoto University
-
〓 尚珍
Institute For Chemical Research Kyoto University
関連論文
- 若い世代に期待する
- エナンチオマーを区別する人工触媒
- より魅力ある日本薬学会誌を目指して
- 炭素アニオン種を活用する新規不斉合成反応の開発
- RADIOSENSITIZING HYPOXIC CELLS WITH NEW 3-NITRO-1,2,4-TRIAZOLE DERIVATIVES IN VITRO AND IN VIVO
- Diastereoselectivity in Addition of Methylmagnesium Halide to Benzoylformate of Chiral 1,1'-Binaphthalene-2,2'-diol
- 10 エナンチオ選択的プロトン化 : 不斉ラクトン化とその天然物合成への応用
- Chiral Piperazines as Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes
- 57 四級炭素の不斉構築 : テルペノイドの全合成への応用(口頭発表の部)
- 64 付加・脱離型不斉誘導 : ラクトン類の不斉ニトロオレフィン化を利用する光学活性インドールアルカロイドの全合成
- The Absolute Configuration of Enmein Transformation of Enmein into (-)-Kaurane
- Lythraceous Alkaloids. XIV. Kinetic Equalization of Carbon-13 Nuclear Magnetic Resonance Chemical Shifts in N, O-Dimethyllythranidine, a Cyclophane Bearing Asymmetric Carbon Atoms
- Lythraceous Alkaloids. XIII. X-Ray Determination of the Molecular Structures of O-Methyllythranidine N, O, O-Triformate, 22-Bromolythranine N, O, O-Triacetate, and O-Methyldeacetyllythramine
- Lythraceous Alkaloids. XII. Circular Dichroism Studies on Lythranine-Type Alkaloids
- Lythraceous Alkaloids. X. Alkaloids of Lagerstroemia subcostata and L. favriei : A Contribution to the Chemotaxonomy
- Lythraceous Alkaloids. II. The Structure of O-Methyllythranidine
- Lythraceous Alkaloids. I. Characterization of the Novel Alkaloids, Lythranine, Lythranidine, and Lythramine isolated from Lythrum anceps MAKINO
- HYBRIDIZATION OF OLIGODEOXYNUCLEOTIDE WITH REXOD COENZYME MODEL; SYNTHESIS AND PROPERTIES OF THYMIDINE DECAMERS COVALENTLY LINKED TO 5-DEAZAFLAVIN
- Use of 1,1'-Binaphthalene-8,8'-diol as a Chiral Auxiliary for Asymmetric Michael Addition. Application to the Syntheses of Turmeronol A and B
- ENHANCED REACTIVITY OF ZINC ENOLATES OVER LITHIUM ENOLATES IN ASYMMETRIC NITROOLEFINATION
- 16 不斉ニトロオレフィン化反応を鍵反応とする光学活性フィゾスチグミンの合成(口頭発表の部)
- Design and Synthesis of Antitumor Compounds Based on the Cytotoxic Diterpenoids from the Genus Rabdosia
- A Chiral Synthesis of a Unique Secodehydroabietane from Tall Oil
- ニトロオレフィンを利用した不斉合成
- Terpenoids. LIV. : The Structures of Rabdoinflexins A and B, New Diterpenoids from Rabdosia inflexa (THUNB.) HARA
- Terpenoids. LIII. : Antitumor Activity of Trichorabdals and Related Compounds
- Terpenoids. LII. : The Structures of Trichorabdal F, Trichorabdal G Acetate, and Trichorabdal H. A Comment on the Structure of Shikodonin
- Terpenoids. LI. : Structures of Antitumor Diterpenoids, Trichorabdals A-E, Isolated from Rabdosia trichocarpa
- THE STRUCTURES OF FOUR NEW DITERPENE ALKALOIDS, SPIRAMINES A, B, C, AND D(Communications to the Editor)
- Terpenoids. L. Antitumor Activity of Diterpenoids from Rabdosia shikokiana var. occidentalis
- Terpenoids. XLVIII. New Diterpenoids from Rabdosia shikokiana var. occidentalis
- ハ-ド酸・ソフト求核剤組合せ系のデザイン--結合開裂反応への応用
- Hard Acid and Soft Nucleophile System. VII. A Convenient Reduction of Functionalized Polyarenes to Parent Polyarenes
- ANTITUMOR ACTIVITY OF DITERPENOIDS, TRICHORABDALS A, B, AND C, AND THE RELATED COMPOUNDS : SYNERGISM OF TWO ACTIVE SITES
- RADICAL CATION INDUCED REDUCTIVE DEHALOGENATION OF ORTHO- AND PARA-HALOPHENOLS AND THEIR DERIVATIVES
- Hard Acid and Soft Nucleophile System. VI. A Convenient Synthesis of Alkylthiopolycyclic Aromatics with a Metal Halide and Thiol System
- 不斉記憶エノレ-ト化学の新しい概念
- P-1 中国産イチイ科植物Taxus chinensisの新ジテルペノイド(ポスター発表の部)
- ON THE STRUCTURES OF SIX NEW DITERPENOIDS, TAXCHININS E, H, I, J, K AND TAXCHIN B
- SELECTIVE DEMETHYLATION OF ALIPHATIC METHYL ETHER IN THE PRESENCE OF AROMATIC METHYL ETHER WITH THE ALUMINUM CHLORIDE-SODIUM IODIDE-ACETONITRILE SYSTEM
- Terpenoids. XLIX. Reactions of Shikoccin : Oxidation, Catalytic Reduction, and Conversion into the Abietane Skeleton
- THREE NEW 8,9-SECO-ENT-KAURANE DITERPENOIDS FROM RABDOSIA SHIKOKIANA (LABIATAE)
- A Chiral Nonracemic Enolate with Dynamic Axial Chirality: Direct Asymmetric Alkylation of α-Amino Acid Derivatives (SYNTHETIC ORGANIC CHEMISTRY-Fine Organic Synthesis)
- Visualization of Molecular Length of α, ω-Diamines and Temperature by a Receptor Based on Phenolphthalein and Crown Ether (SYNTHETIC ORGANIC CHEMISTRY-Fine Organic Synthesis)
- Synthesis of Extremely Simplified Compounds Possessing the Key Pharmacophore Units of Taxol, Phenylisoserine and Oxetane Moieties
- The First Synthesis of an Optically Active Molecular Bevel Gear with Only Two Cogs on Each Wheel (SYNTHETIC ORGANIC CHEMISTRY-Fine Organic Synthesis)
- 光学活性リン試薬を用いる不斉レフィン化
- Effects of Cholesterol on the Miscibility of Synthetic Glucosamine Diesters in Lipid Bilayers and the Entrapment of Superoxide Dismutase into the Positively Charged Liposomes
- THREE NEW DITERPENOIDS FROM TAXUS CHINENSIS
- Hard Acid and Soft Nucleophile Systems. Part 13. Aluminum Chloride-Sodium Iodide-Acetonitrile System : A Very Mild Reagent for Selective Dealkylation (Commemoration Issue Dedicated to Professor Shigeo Tanimoto On the Occation of His Retirement)
- SYNTHESIS, STRUCTURE, AND SELF-OXIDATION OF ALKYNYL(PHENYL)IODONIUM PERIODATES
- Regioselective Hydroxylation in the C Ring of ent-Kaurene ; Syntheses of ent-11α-Hydroxykaurene and ent-11α-Hydroxykauren-15-one
- Hard Acid and Soft Nucleophile System. IV. Removal of Benzyl Protecting Group with Boron Trifluoride Etherate and Dimethyl Sulflide
- Terpenoids. XXXVII. Hypoiodite Reactions with 6-Hydroxy-17-norkaurane- and 7-Norgibberellane-derivatives
- A Versatile Synthesis of (±)-Solenopsin A
- The First Example for Cycloenantiomeric Hexahomooxacalix[3]arenes
- The '2+1' Construction of Homooxacalix[3]arenes Possessing Different Substituents on Their Upper Rims
- Preparation of Nitroalkenes : Substitution Reaction via Addition-Elimination Using β-Nitrovinyl Sulfoxides.
- Hard Acid and Soft Nucleophile Systems. Part 12. : Regioselective Functionalization of 1,3-Dienes through the Lewis Acid Mediated Thienium Cation Diels-Alder Reaction.
- Asymmetric Diels-Alder Cycloaddition with Chiral 2-Alkylsulfinyl-1-nitroalkenes.
- PB133 ENANTIOSELECTIVE TOTAL SYNTHESES OF (+)-PODOCARPIC ACID AND RELATED DITERPENOIDS
- Addition-Elimination Strategy for Asymmetric Induction : A Chiral Sulfoxide as a Leaving Group.
- 実用的な有機合成反応
- 薬学における有機合成の現状と将来
- A Formal Asymmetric Synthesis of Calabar Bean Alkaloids
- New Chiral Shift Reagents, Optically Active 2,2'-Dihydroxy-1,1'-binaphthyl and 1,6-Di(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol.
- Conformational Difference between Mono- and Diprotonated cis-2,5-Diphenylpiperazinium Salts in the Solid State
- 不斉記憶
- フェノールフタレインを組み込んだ呈色型分子の開発
- Conformation of 1, 4-Dineopentyl-2, 5-cis-diphenylpiperazinc and Its Diammonium Salts : Remarkable Change in Conformation Depending upon the Counter Anion
- A Total Synthesis of (-)-Physostigmine.
- ニトロオレフィンを利用した不斉合成
- 各種結合の選択的開裂に有用なハード酸-ソフト求核剤組合せ系新反応剤の開発研究
- ハード酸・ソフト求核剤組合せ系のデザイン : 結合開裂反応への応用
- 反常識の化学
- 日本薬学会奨励賞受賞川端猛夫氏の業績
- 日本薬学会技術賞「セフェム系経口剤「セフィキシム」および「セフジニル」の研究開発」
- リスラニン型ミソハギアルカロイド, (±)-Lythranidineの合成研究
- 反応と合成の進歩シンポジウム