SYNTHESIS, STRUCTURE, AND SELF-OXIDATION OF ALKYNYL(PHENYL)IODONIUM PERIODATES
スポンサーリンク
概要
- 論文の詳細を見る
Synthesis and characterization of alkynyl(phenyl)iodonium periodate (2__〜) are described;on standing at room temperature, the product undergoes the carbon-carbon triple bond cleavage by self-oxidation with the counter anion, IO_4^-.
- 公益社団法人日本薬学会の論文
- 1989-07-25
著者
-
城 始勇
Research And Development Division Rigaku Industrial Corporation
-
冨士 薫
Institute For Chemical Research Kyoto University
-
長尾 善光
Institute for Chemical Research, Kyoto University
-
落合 正仁
Institute for Chemical Research, Kyoto University
-
国嶋 崇隆
Institute for Chemical Research, Kyoto University
-
城 始勇
Japan and Shionogi Research Laboratories, Shionogi & Co. Ltd.,
-
長尾 善光
Institute For Chemical Research Kyoto University
-
国嶋 崇隆
Institute For Chemical Research Kyoto University
-
落合 正仁
Institute For Chemical Research Kyoto University
関連論文
- ISOLATION AND STRUCTURE ELUCIDATION OF NEW ALKALOIDS FROM FRITILLARIA DELAVAYI FRANCH
- Revised Structure of a Novel Disaccharide, Wilforibiose, Obtained from the Hydrolysate of Cynanchum wilfordi HEMSLEY Glycosides
- RADIOSENSITIZING HYPOXIC CELLS WITH NEW 3-NITRO-1,2,4-TRIAZOLE DERIVATIVES IN VITRO AND IN VIVO
- Diastereoselectivity in Addition of Methylmagnesium Halide to Benzoylformate of Chiral 1,1'-Binaphthalene-2,2'-diol
- SYNTHESIS OF 9,9,9-TRIFLUORO-2-p-MENTHENE-1,8-DIOL. DETERMINATION OF THE STRUCTURE BY X-RAY ANALYSIS
- Chiral Piperazines as Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes
- Monitored Aminolysis of 3-Acyl-1,3-thiazolidine-2-thiones : Synthesis of Amides and Amide Alkaloids
- Tortifoline, a Novel (20S, 22R)-5α-Cevanine Alkaloid from Fritillaria tortifolia
- The Structural Elucidation of Fritillaria Alkaloids from Fritillaria ebeiensis var. purpurea. I. : The Structures of Ebeienine, Ebeiedine and Ebeiedinone
- 14 抗生物質合成に有用な新しい高選択的不斉誘導
- Terpenoids. XVII. Chemical Conversion of Trichokaurin into Isodocarpin via a Direct Pathway
- The Absolute Configuration of Enmein Transformation of Enmein into (-)-Kaurane
- Lythraceous Alkaloids. XIV. Kinetic Equalization of Carbon-13 Nuclear Magnetic Resonance Chemical Shifts in N, O-Dimethyllythranidine, a Cyclophane Bearing Asymmetric Carbon Atoms
- Lythraceous Alkaloids. XIII. X-Ray Determination of the Molecular Structures of O-Methyllythranidine N, O, O-Triformate, 22-Bromolythranine N, O, O-Triacetate, and O-Methyldeacetyllythramine
- Lythraceous Alkaloids. XII. Circular Dichroism Studies on Lythranine-Type Alkaloids
- Lythraceous Alkaloids. X. Alkaloids of Lagerstroemia subcostata and L. favriei : A Contribution to the Chemotaxonomy
- Lythraceous Alkaloids. II. The Structure of O-Methyllythranidine
- Lythraceous Alkaloids. I. Characterization of the Novel Alkaloids, Lythranine, Lythranidine, and Lythramine isolated from Lythrum anceps MAKINO
- HYBRIDIZATION OF OLIGODEOXYNUCLEOTIDE WITH REXOD COENZYME MODEL; SYNTHESIS AND PROPERTIES OF THYMIDINE DECAMERS COVALENTLY LINKED TO 5-DEAZAFLAVIN
- Use of 1,1'-Binaphthalene-8,8'-diol as a Chiral Auxiliary for Asymmetric Michael Addition. Application to the Syntheses of Turmeronol A and B
- Spectroscopic Identification of 3-Substituted 4-Methoxycarbonyl-1,3-thiazolidine(or-oxazolidine)-2-thiones and 2-Substituted Thio-4-methoxycarbonyl-Δ^2-1,3-thiazolines(or -oxazolines)
- Substituent Effect of the Benzene Ring on Thermal Rearrangement of the Substituted Benzyl Group from exo-S to N(3) in (rac)2-Substituted Benzylthio-4-methoxycarbonyl-Δ^2-1,3-thiazolines
- Syntheses of (rac)3-Substituted 4-Methoxycarbonyl-1,3-thiazolidine-2-thiones via Rearrangement of a Substituted Group from exo-S to N in (rac)2-Substituted Thio-4-methoxyarbonyl-Δ^2-1,3-thiazolines
- Studies on Digitalis Glycosides. XXXVII. Diels-Alder Reaction of 16,17-Dehydrodigitoxigenin 3-Acetate (2)
- ENHANCED REACTIVITY OF ZINC ENOLATES OVER LITHIUM ENOLATES IN ASYMMETRIC NITROOLEFINATION
- Design and Synthesis of Antitumor Compounds Based on the Cytotoxic Diterpenoids from the Genus Rabdosia
- A Chiral Synthesis of a Unique Secodehydroabietane from Tall Oil
- Terpenoids. LIV. : The Structures of Rabdoinflexins A and B, New Diterpenoids from Rabdosia inflexa (THUNB.) HARA
- Terpenoids. LIII. : Antitumor Activity of Trichorabdals and Related Compounds
- Terpenoids. LII. : The Structures of Trichorabdal F, Trichorabdal G Acetate, and Trichorabdal H. A Comment on the Structure of Shikodonin
- Terpenoids. LI. : Structures of Antitumor Diterpenoids, Trichorabdals A-E, Isolated from Rabdosia trichocarpa
- THE STRUCTURES OF FOUR NEW DITERPENE ALKALOIDS, SPIRAMINES A, B, C, AND D(Communications to the Editor)
- Terpenoids. L. Antitumor Activity of Diterpenoids from Rabdosia shikokiana var. occidentalis
- Terpenoids. XLVIII. New Diterpenoids from Rabdosia shikokiana var. occidentalis
- Hard Acid and Soft Nucleophile System. VII. A Convenient Reduction of Functionalized Polyarenes to Parent Polyarenes
- RADICAL CATION INDUCED REDUCTIVE DEHALOGENATION OF ORTHO- AND PARA-HALOPHENOLS AND THEIR DERIVATIVES
- Constituents of Cimicifugae Rhizoma. I. Isolation and Characterization of Ten New Cycloartenol Triterpenes from Cimicifuga heracleifolia KOMAROV
- TRIFLUOROMETHYLATION OF CHIRAL ALDEHYDE AND SYNTHESIS OF 6-DEOXY-6,6,6-TRIFLUOROHEXOSES
- Studies on the Acyl Glycosides from Leucoseptrum japonicum (MIQ.) KITAMURA et MURATA
- P-1 中国産イチイ科植物Taxus chinensisの新ジテルペノイド(ポスター発表の部)
- ON THE STRUCTURES OF SIX NEW DITERPENOIDS, TAXCHININS E, H, I, J, K AND TAXCHIN B
- SELECTIVE DEMETHYLATION OF ALIPHATIC METHYL ETHER IN THE PRESENCE OF AROMATIC METHYL ETHER WITH THE ALUMINUM CHLORIDE-SODIUM IODIDE-ACETONITRILE SYSTEM
- Terpenoids. XLIX. Reactions of Shikoccin : Oxidation, Catalytic Reduction, and Conversion into the Abietane Skeleton
- THREE NEW 8,9-SECO-ENT-KAURANE DITERPENOIDS FROM RABDOSIA SHIKOKIANA (LABIATAE)
- Antitumor Activity of Rabdosia and Teucrium Diterpenoids against P 388 Lymphocytic Leukemia in Mice
- A Chiral Nonracemic Enolate with Dynamic Axial Chirality: Direct Asymmetric Alkylation of α-Amino Acid Derivatives (SYNTHETIC ORGANIC CHEMISTRY-Fine Organic Synthesis)
- Visualization of Molecular Length of α, ω-Diamines and Temperature by a Receptor Based on Phenolphthalein and Crown Ether (SYNTHETIC ORGANIC CHEMISTRY-Fine Organic Synthesis)
- Synthesis of Extremely Simplified Compounds Possessing the Key Pharmacophore Units of Taxol, Phenylisoserine and Oxetane Moieties
- The First Synthesis of an Optically Active Molecular Bevel Gear with Only Two Cogs on Each Wheel (SYNTHETIC ORGANIC CHEMISTRY-Fine Organic Synthesis)
- 光学活性リン試薬を用いる不斉レフィン化
- Effects of Cholesterol on the Miscibility of Synthetic Glucosamine Diesters in Lipid Bilayers and the Entrapment of Superoxide Dismutase into the Positively Charged Liposomes
- THREE NEW DITERPENOIDS FROM TAXUS CHINENSIS
- Hard Acid and Soft Nucleophile Systems. Part 13. Aluminum Chloride-Sodium Iodide-Acetonitrile System : A Very Mild Reagent for Selective Dealkylation (Commemoration Issue Dedicated to Professor Shigeo Tanimoto On the Occation of His Retirement)
- SYNTHESIS, STRUCTURE, AND SELF-OXIDATION OF ALKYNYL(PHENYL)IODONIUM PERIODATES
- Regioselective Hydroxylation in the C Ring of ent-Kaurene ; Syntheses of ent-11α-Hydroxykaurene and ent-11α-Hydroxykauren-15-one
- SYNTHESIS OF A COMPOUND HAVING A PALUSTRINE STRUCTURE
- Hard Acid and Soft Nucleophile System. IV. Removal of Benzyl Protecting Group with Boron Trifluoride Etherate and Dimethyl Sulflide
- Simmons-Smith Reactions of Fluoroallyl Alcohol Derivatives
- 13 核間窒素原子を有する二環性アルカロイドの単純化不斉合成(口頭発表の部)
- A CONVENIENT METHOD FOR THE SYNTHESIS OF αβ-UNSATURATED CARBOXYLIC ACID AMIDES UTILIZING A NEW HETERO-BIFUNCTIONAL REAGENT, DMPATT
- Silicon-Assisted Ring Opening of Cyclopropyl Ketones with Boron Trifluoride-Acetic Acid Complex
- Stereoselective Syntheses of E- and Z-9,11-Dodecadien-1-yl Acetates : The Major Sex Pheromones of the Red Bollworm Moth
- Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane via Their Reaction with Thallium (III) Salt : A New Allylation Reaction for Aromatic Compounds
- Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane : Allylation of Aromatic Compounds with Allylmetal and Arylthallium Bis (trifluoroacetate)
- Terpenoids. XLIII. Total Synthesis of rac-Kaur-16-ene-11α, 15α-diol
- Terpenoids. XLII. A Convenient Stereoselective Transformation of 16-Exocyclic Methylene Group into Carboxy Group in ent-Kaurene and Its 19-Oic Acid
- Iodine (III)-Mediated Intramolecular Cyclization of Hydroxy Allylsilanes : Synthesis of 5- or 6-Membered β-Methylene Cyclic Ethers
- Iodine (III)-Mediated Allylation of Aromatic Compounds and Alcohols Using Allylmetal (Group IVb) Compounds
- Thallium (III)-Mediated Allylation of Alcohols and Carboxylic Acids : Umpolung of Reactivity of Allylmetal (Group IVb) Compounds
- Facile 1,4-Silyl Rearrangement with Concomitant Loss of a Benzenesulfonyl Group : One-Pot Synthesis of Allyloxysilanes
- Diazidation of Allylsilanes with a Combination of Iodosylbenzene and Trimethylsilyl Azide, and Synthesis of Allyl Azides
- プロキラルなσ-対称分子への高選択的不斉誘導 (精密合成化学--21世紀を担う若い化学者へ)
- スペルミジンシデロホア,パラバクチンの全合成(発表論文抄録(1984年),福山大学開学10周年記念号)
- 62 機能性複素五員環を活用するVirginiamycin M2の全合成研究
- Antitumor Activity of Acylated Oridonin
- An Efficient Method for Selective Acetylation of Alcoholic Hydroxyl Groups
- 62 Spermidine siderophoresの全合成研究
- Utilization of Derivatives of Thiazolidine-2-thione : Esterification
- Useful Dethioacetalization with Soft Acid Metal Salts : Thallium Trinitrate and Mercuric Perchlorate
- Dethioacetalization with Thallium (III) Nitrate
- ELECTROPHILIC CYCLIZATION REACTION OF gem-DIFLUOROOLEFIN DERIVATIVES : SYNTHESES OF 6,6-DIFLUOROTETRAHYDRO-2-PYRONES AND 2,2-DIFLUOROTETRAHYDROPYRAN via HALOGEN INDUCED CYCLIZATION
- 61 新しい不斉アルキル化デザインを基盤とする二環性アルカロイド合成(口頭発表の部)
- GANODERIC ACIDS T, S AND R, NEW TRITERPENOIDS FROM THE CULTURED MYCELIA OF GANODERMA LUCIDUM
- The Crystal Structure of Securinine Hydrobromide Dihydrate and the Molecular Structure of Securinine
- A Versatile Synthesis of (±)-Solenopsin A
- The First Example for Cycloenantiomeric Hexahomooxacalix[3]arenes
- The '2+1' Construction of Homooxacalix[3]arenes Possessing Different Substituents on Their Upper Rims
- Preparation of Nitroalkenes : Substitution Reaction via Addition-Elimination Using β-Nitrovinyl Sulfoxides.
- Hard Acid and Soft Nucleophile Systems. Part 12. : Regioselective Functionalization of 1,3-Dienes through the Lewis Acid Mediated Thienium Cation Diels-Alder Reaction.
- Asymmetric Diels-Alder Cycloaddition with Chiral 2-Alkylsulfinyl-1-nitroalkenes.
- PB133 ENANTIOSELECTIVE TOTAL SYNTHESES OF (+)-PODOCARPIC ACID AND RELATED DITERPENOIDS
- Addition-Elimination Strategy for Asymmetric Induction : A Chiral Sulfoxide as a Leaving Group.
- A Formal Asymmetric Synthesis of Calabar Bean Alkaloids
- メチルセレノ基によって促進されるケテン-イミン環化反応を活用するペナム型β-ラクタムの簡便合成 (ヘテロ原子の有機化学) -- (6族元素(硫黄,セレン,テルル))
- 注目されるβ-ラクタム系抗生物質--1β-置換カルバペネムの合成
- エステルエノレートアルキル化反応におけるアリル位置換基の立体電子的効果
- New Chiral Shift Reagents, Optically Active 2,2'-Dihydroxy-1,1'-binaphthyl and 1,6-Di(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol.
- Conformational Difference between Mono- and Diprotonated cis-2,5-Diphenylpiperazinium Salts in the Solid State
- Conformation of 1, 4-Dineopentyl-2, 5-cis-diphenylpiperazinc and Its Diammonium Salts : Remarkable Change in Conformation Depending upon the Counter Anion
- A Total Synthesis of (-)-Physostigmine.