Iodine (III)-Mediated Allylation of Aromatic Compounds and Alcohols Using Allylmetal (Group IVb) Compounds

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概要

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• The reaction of allylmetal (group IVb) compounds with aromatic compounds and iodosylbenzene in the presence of BF_3-Et_2O afforded the corresponding allylation products. Allylation of alcohols was also carried out to give allyl ethers. The activation of iodosylbenzene by the coordination of BF_3-Et_2O was assumed to be one of the most important factors for the reaction. The involvement of the reactive allyliodine (III) compounds in these reactions is discussed.

• 公益社団法人日本薬学会の論文
• 1985-01-25

著者

• 山口 秀夫

  Osaka University of Pharmaceutical Sciences

• 藤田 榮一

  Osaka University of Pharmaceutical Sciences

• 落合 正仁

  Institute for Chemical Research, Kyoto University

• 藤田 栄一

  京都大学化学研究所

• 藤田 栄一

  Osaka University Of Pharmaceutical Sciences

• 有本 正生

  Osaka College of Pharmacy

• 藤田 榮一

  Institute for Chemical Research, Kyoto University

• 有本 正生

  大阪薬大

• 落合 正仁

  Institute For Chemical Research Kyoto University

• 落合 正仁

  徳島大学大学院ヘルスバイオサイエンス研究部精密薬品製造学分野

• 有本 正生

  Osaka University Of Pharmaceutical Sciences

• 落合 正仁

  京都大学化学研究所

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