Thallium (III)-Mediated Allylation of Alcohols and Carboxylic Acids : Umpolung of Reactivity of Allylmetal (Group IVb) Compounds

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概要

• 論文の詳細を見る

• A new general method for the synthesis of allyl ethers and allyl acetates is described. Allylmetal (group IVb) compounds, on treatment with thallium (III) salts in alcohols or acetic acid, gave the corresponding allyl ethers or allyl acetates in good yields. The reaction was successfully applied to the synthesis of the 6-membered cyclic ether 20 via the intramolecular, thallium (III)-mediated allylation reaction of the allylsilane 18.

• 公益社団法人日本薬学会の論文
• 1984-12-25

著者

• 山口 秀夫

  Osaka University of Pharmaceutical Sciences

• 藤田 榮一

  Osaka University of Pharmaceutical Sciences

• 落合 正仁

  Institute for Chemical Research, Kyoto University

• 藤田 栄一

  京都大学化学研究所

• 藤田 栄一

  Osaka University Of Pharmaceutical Sciences

• 有本 正生

  Osaka College of Pharmacy

• 藤田 榮一

  Institute for Chemical Research, Kyoto University

• 有本 正生

  大阪薬大

• 落合 正仁

  Institute For Chemical Research Kyoto University

• 落合 正仁

  徳島大学大学院ヘルスバイオサイエンス研究部精密薬品製造学分野

• 有本 正生

  Osaka University Of Pharmaceutical Sciences

• 落合 正仁

  京都大学化学研究所

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