Terpenoids. XLII. A Convenient Stereoselective Transformation of 16-Exocyclic Methylene Group into Carboxy Group in ent-Kaurene and Its 19-Oic Acid
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概要
- 論文の詳細を見る
By the two successive oxidative rearrangements using thallium trinitrate, ent-16-kaurene (1) was stereoselectively converted into ent-16α-kauran-17-oic acid (30). Further application of these reactions led to a convenient transformation of ent-16-kauren-19-oic aicd (31) into ent-16α-kaurane-17,19-dioci acid (32).
- 公益社団法人日本薬学会の論文
- 1977-11-25
著者
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落合 正仁
Institute for Chemical Research, Kyoto University
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藤田 栄一
京都大学化学研究所
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藤田 栄一
Osaka University Of Pharmaceutical Sciences
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藤田 栄一
Institute for Chemical Research, Kyoto University
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藤田 栄一
Institute For Chemical Research Kyoto University
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落合 正仁
Institute For Chemical Research Kyoto University
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落合 正仁
徳島大学大学院ヘルスバイオサイエンス研究部精密薬品製造学分野
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落合 正仁
京都大学化学研究所
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