Diazidation of Allylsilanes with a Combination of Iodosylbenzene and Trimethylsilyl Azide, and Synthesis of Allyl Azides

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概要

• 論文の詳細を見る

• Reaction of Allyltrimethylsilanes with iodosylbenzene and trimethylsilyl azide in dichloromethane at -78 ℃ to room temperature affords vicinal diazides, which undergo fluoride ion-catalyzed β-elimination of azide and trimethylsilyl groups, providing allyl azides in good yields.

• 公益社団法人日本薬学会の論文
• 1989-12-25

著者

• 山口 秀夫

  Osaka University of Pharmaceutical Sciences

• 藤田 榮一

  Osaka University of Pharmaceutical Sciences

• 長尾 善光

  Institute for Chemical Research, Kyoto University

• 落合 正仁

  Institute for Chemical Research, Kyoto University

• 藤田 栄一

  京都大学化学研究所

• 藤田 栄一

  Osaka University Of Pharmaceutical Sciences

• 有本 正生

  Osaka College of Pharmacy

• 長尾 善光

  Institute For Chemical Research Kyoto University

• 有本 正生

  大阪薬大

• 落合 正仁

  Institute For Chemical Research Kyoto University

• 有本 正生

  Osaka University Of Pharmaceutical Sciences

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