Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane : Allylation of Aromatic Compounds with Allylmetal and Arylthallium Bis (trifluoroacetate)

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概要

• 論文の詳細を見る

• A direct allylation of aromatic compounds using allylsilane, allylgermane, or allylstannane (1) and arylthallium bis (trifluoroacetate) has been developed. The actual transmetalation reagent for 1 in the reaction was proposed to be thallium (III) trifluoroacetate (2), which was produced together with diarylthallium trifluoroacetate by the disproportionation of arylthallium bis (trifluoroacetate).

• 公益社団法人日本薬学会の論文
• 1982-11-25

著者

• 山口 秀夫

  Osaka University of Pharmaceutical Sciences

• 落合 正仁

  Institute for Chemical Research, Kyoto University

• 藤田 栄一

  京都大学化学研究所

• 藤田 栄一

  Osaka University Of Pharmaceutical Sciences

• 藤田 栄一

  Institute for Chemical Research, Kyoto University

• 有本 正生

  Osaka College of Pharmacy

• 藤田 栄一

  Institute For Chemical Research Kyoto University

• 有本 正生

  大阪薬大

• 落合 正仁

  Institute For Chemical Research Kyoto University

• 落合 正仁

  徳島大学大学院ヘルスバイオサイエンス研究部精密薬品製造学分野

• 有本 正生

  Osaka University Of Pharmaceutical Sciences

• 落合 正仁

  京都大学化学研究所

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