Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane via Their Reaction with Thallium (III) Salt : A New Allylation Reaction for Aromatic Compounds

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概要

• 論文の詳細を見る

• A new direct allylation of aromatic compounds has been developed. A mixture of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate was allowed to react with an aromatic compound, a nucleophile, to give allylation product (s) in good yields via an allylcationic species. Thus, the usefulness of these allylmetal compounds as allyl cation equivalents was established.

• 公益社団法人日本薬学会の論文
• 1983-01-25

著者

• 山口 秀夫

  Osaka University of Pharmaceutical Sciences

• 落合 正仁

  Institute for Chemical Research, Kyoto University

• 藤田 栄一

  京都大学化学研究所

• 藤田 栄一

  Osaka University Of Pharmaceutical Sciences

• 藤田 栄一

  Institute for Chemical Research, Kyoto University

• 有本 正生

  Osaka College of Pharmacy

• 藤田 栄一

  Institute For Chemical Research Kyoto University

• 有本 正生

  大阪薬大

• 落合 正仁

  Institute For Chemical Research Kyoto University

• 落合 正仁

  徳島大学大学院ヘルスバイオサイエンス研究部精密薬品製造学分野

• 有本 正生

  Osaka University Of Pharmaceutical Sciences

• 落合 正仁

  京都大学化学研究所

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