Raman Scattering by Ethylenediamines in Quasi-One-Dimensional Mixed-Valence Complexes [M (en)_2][Pt (en)_2Cl_2](ClO_4)_4(M=Pt,Pd,en=ethylenediamine)

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概要

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• We have studied the effect of the order-disorder transition of the orientation ofperchlorate (C10j ) ions on the vibrational modes of ethylenediamine(NH.CH.CH.NH.) in [M(en).][Pt(en).C1z](CIO.)., where en is ethylenediamine andM = Pt or Pd ion, by means of Raman spectroscopy. Upon the transition into the or-dered phase, the spectra due to the CH stretching modes split into two groups on ac-count of the difference in the coordination sites of Pt(II)[Pd(II)] and Pt(IV). The spec-Crab separation between the two groups is about 20 cm at 270 K. On the other hand,the NH stretching and the NCCN skeleton modes exhibit no splitting. These results indicate that the protons of the methylene (Cl.) group of the ethylenediamine have astrong interaction with the internal motion of the perchlorate ions which bind theCDW chains.[Raman scattering, ethylenediamine, one-dimensional mixed-valence, per- ]I chlorate, order-disorder transitionll

• 社団法人日本物理学会の論文
• 1991-05-15

著者

• Sakai Masamichi

  Institute for Materials Research, Tohoku University

• Kuroda Noritaka

  Institute for Materials Research, Tohoku University

• Nishina Yuichiro

  Institute for Materials Research, Tohoku University

• Yamashita Masahiro

  Department Of Bioengineering Tokyo Institute Of Technology

• 黒田 規敬

  熊本大学大学院

• 山下 護

  徳島工短

• 山下 護

  Department Of Physics Engineering Faculty Of Engineering Mie University

• Kuroda Noritaka

  Discovery Research Laboratories V Discovery Research Division Takeda Chemical Industries Ltd.

• Kuroda Noritaka

  Institute For Materials Science Tohoku University

• Kuroda Noritaka

  Institute For Materials Research Tohoku University

• Nishina Yuichiro

  Institute For Materials Research (imr) Tohoku University

• Sakai M

  Tohoku Univ. Sendai

• Yamashita Makoto

  Department Of Applied Physics Osaka University

• HAYAKAWA Masayumi

  Institute for Materials Research,Tohoku University

• Hayakawa M

  Institute For Materials Research Tohoku University

• Yamashita Masahiro

  Department Of Chemistry Faculty Of Science Tokyo Metropolitan University

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