Photoinduced Near-Infrared Absorption in an M-X Chain Complex [Pt(en)_2][Pt(en)_2Cl_2](ClO_4)_4, en = ethylenediamine

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概要

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• The near-infrared absorption spectrum has been measured in [Pt(en)_2][Pt(en)_2Cl_2](ClO_4)_4, (en)=ethylenediamine, irradiated with the 488 nm beam of an Ar-ion laser. In addition to the well-established intragap bands A around 1.6 eV and B around 2.0 eV, a broad band B' is found to overlap the B band and be spread beyond 2.3 eV. No bands can be found at photon energies down to 1.2 eV below the A band. The results are discussed in relation to the "two-band" theory for polarons and solitons by Tinka-Gammel and coworkers (Phys. Rev. B45 (1992) 6435).

• 社団法人日本物理学会の論文
• 1993-07-15

著者

• Kuroda Noritaka

  Institute for Materials Research, Tohoku University

• Nishina Yuichiro

  Institute for Materials Research, Tohoku University

• 黒田 規敬

  熊本大学大学院

• 仁科 雄一郎

  東北大学金属材料研究所

• 山下 護

  徳島工短

• 山下 護

  Department Of Physics Engineering Faculty Of Engineering Mie University

• Ito M

  Institute For Materials Research Tohoku University

• Kuroda Noritaka

  Discovery Research Laboratories V Discovery Research Division Takeda Chemical Industries Ltd.

• Kuroda Noritaka

  Institute For Materials Science Tohoku University

• Kuroda Noritaka

  Institute For Materials Research Tohoku University

• Nishina Yuichiro

  Institute For Materials Research (imr) Tohoku University

• Nishina Yuichiro

  Institute Of Materials Resesrch Tohoku University

• Yamashita Makoto

  Department Of Applied Physics Osaka University

• Ito Motoki

  Institute for Materials Research, Tohoku University

• Yamashita Masahiro

  College of General Education, Nagoya University

• Kuroda N

  Nec Corp. Ibaraki Jpn

• Ito Motoki

  Institute For Materials Research Tohoku University

• Yamashita Masahiro

  College Of General Education Kyushu University

• Yamashita Masahiro

  Department Of Chemistry Faculty Of Science Tokyo Metropolitan University

• KURODA Noritaka

  Research Institute for Iron, Steel and Other Metals Tohoku University : Tohoku University : Physics Department, Purdue University

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