Steric and Electronic Effects of Substrates and Rhodium Chiral Catalysts in Asymmetric Cyclopropanation
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概要
- 論文の詳細を見る
We have prepared several new, efficient, chiral N-acyl pyrrolidine carboxylic acid ligands for dirhodium-catalyzed asymmetric cyclopropanation and found that the steric and electronic effects of the rhodium(II) complexes and substrates influenced the enantioselectivity and catalytic activity. These electron-rich catalysts were shown to be efficient for asymmetric cyclopropanation using 1-chloro-1-fluoroethylene as a substrate.
- 公益社団法人日本薬学会の論文
- 1995-12-15
著者
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阿知波 一雄
静岡県立大学薬学部
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阿知波 一雄
School of Pharmaceutical Sciences, University of Shizuoka
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阿知波 一雄
静岡県大薬
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阿知波 一雄
東大・薬
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吉川 清史
School of Pharmaceutical Sciences, University of Shizuoka
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吉川 清史
School Of Pharmaceutical Sciences University Of Shizuoka
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Yoshikawa Kiyoshi
School Of Pharmaceutical Sciences University Of Shizuoka
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Achiwa Kazuo
School Of Pharmaceutical Sciences(laboratory Of Medicinal Chemistry)
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