Studies on the Constitutents of Aster scaber THUNB. V. Structures of Six New Echinocystic Acid Glycosides Isolated from the Herb
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概要
- 論文の詳細を見る
Six new echinocystic acid 3,28-O-bisdesmosides, scaberosides Hc_2,Hd, Hf, Hg, Hh and Hi, were isolated as their methyl esters from the ground part of Aster scaber THUNB. (Compositae), and their structures were determined based on spectral and chemical evidence as follows. Scaberoside Hc_2 is 3-O-[O-β-D-xylopyranosyl-(1→3)-β-D-glucopyranosiduronic acid] echinocystic acid 28-{O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl}ester, scaberoside Hd, 3-O-[O-β-D-xylopyranosyl-(1→3)-β-D-glucopyranosiduronic acid] echinocystic acid 28-{O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→3)-[O-β-D-xylopyranosyl-(1→4)]-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl} ester, scaberoside Hf, 3-O-[O-β-D-galactopyranosyl-(1→2)-β-D-glucopyranosiduronic acid] echinocystic acid 28-{O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl} ester, scaberoside Hg, 3-O-[O-β-D-galactopyranosyl-(1→2)-β-D-glucopyranosiduronic acid] echinocystic acid 28-{O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl} ester, scaberoside Hh, 3-O-{O-β-D-galactopyranosyl-(1→2)-[O-β-D-xylopyranosyl-(1→3)]-β-D-glucopyranosiduronic acid} echinocystic acid 28-{O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl} ester and scaberoside Hi, 3-O-[O-β-D-galactopyranosyl-(1→2)-β-D-glucopyranosiduronic acid] echinocystic acid 28-{O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→3)-[O-β-D-xylopyranosyl-(1→4)]-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl} ester.
- 公益社団法人日本薬学会の論文
- 1993-09-15
著者
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長尾 常敦
福岡大
-
岡部 光
Faculty Of Pharmaceutical Sciences Fukuoka University
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岩瀬 由紀子
福岡大学薬学部
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岡部 光
福岡大学
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Okabe Hikaru
福岡大学 薬学部
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岡部 光
福岡大学薬学部
-
岩瀬 由紀子
Faculty of Pharmaceutical Sciences, Fukuoka University
-
長尾 常敦
Faculty of Pharmaceutical Sciences, Fukuoka University
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