Studies on the Constituents of Aster tataricus L. f. IV. : Structures of Aster Saponins Isolated from the Herb
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概要
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Five echinocystic acid glucuronide saponins, aster saponins Ha, Hb, Hc, Hd and foetidissimoside A (=kirengesho-masaponin I), were isolated from the ground part of Aster tataricus L. f. (Compositae) as their methyl esters, and their structures were determined based on spectral evidence and chemical degradation. These saponins have a common prosapogenin structure, echinocystic acid-3-O-glucopyranosiduronic acid, and differ in the structures of the 28-O-linked sugar moieties.Aster saponin Ha is a 28-[α-L-arabinopyranosyl]ester, Hb, a 28-[O-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl] ester Hc, a 28-[O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl] ester and Hd, a 28-[O-β-D-xylopyranosyl-(1→3)-O-β-D-sylopyranosyl-(1→4)-[O-β-D-apiofuranosyl-(1→3)]-O-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl] ester of the prosapogenin.
- 1990-05-25
著者
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長尾 常敦
福岡大
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岡部 光
Faculty Of Pharmaceutical Sciences Fukuoka University
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岡部 光
福岡大学
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Okabe Hikaru
福岡大学 薬学部
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田中 龍一郎
Faculty of Pharmaceutical Sciences, Setsunan University
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山内 辰郎
福岡大学薬学部
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山内 辰郎
Faculty of Pharmaceutical Sciences, Fukuoka University
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長尾 常敦
Faculty of Pharmaceutical Sciences, Fukuoka University
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山内 辰郎
Faculty Of Pharmaceutical Sciences Fukuoka University
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田中 龍一郎
Faculty Of Pharmaceutical Sciences Fukuoka University
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