Studies on the Constituents of Actinostemma lobatum MAXIM. V. : Structures of Lobatosides B, E, F and G, the Dicrotalic Acid Esters of Bayogenin Bisdesmosides Isolated from the Herb

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• The structures of lobatosides B, E, F and G, the dicrotalic acid esters of bayogenin bisdesmosides isolated from the harb of Actinostemma lobatum MAXIM. (Cucurbitaceae), were determined on the basis of chemical and spectral evidence.Lobatoside B is the dicrotalic acid (3-hydroxy-3-methylglutaric acid) ester of 3-O-[β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl]bayogenin 28-[α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl] ester. Dicrotalic acid is linked at one end to the C_6-hydroxyl group of the terminal β-D-glucopyranosyl group in the C_3-linked sugar moiety, and at the other end to the C_4-hydroxyl group of the α-L-rhamnopyranosyl group in the ester-linked sugar moiety to form a macrocyclic structure (cyclic bisdesmoside).Lobatosides E, F and G are cyclic bisdesmosides of bayogenin similar to lobatoside B, but different in the numbers and species of the component sugars and positions of the ester linkages of the dicrotalic acid.

• 社団法人日本薬学会の論文
• 1989-09-25

著者

• 藤岡 稔大

  福岡大学薬学部

• 三橋 國英

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 岡部 光

  Faculty Of Pharmaceutical Sciences Fukuoka University

• 岩瀬 由紀子

  福岡大学薬学部

• 三橋 国英

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 岡部 光

  福岡大学

• Okabe Hikaru

  福岡大学 薬学部

• 岩瀬 由紀子

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 山内 辰郎

  福岡大学薬学部

• 山内 辰郎

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 三橋 國英

  福山大学薬学部

• 三橋 国英

  Faculty Of Pharmaceutical Sciences Fukuoka University

• 三橋 國英

  Faculty Of Pharmaceutical Sciences Fukuoka University

• 藤岡 稔大

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 岩元 雅代

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 八山 しづ子

  Faculty of Pharmaceutical Sciences, Fukuoka University

• 岩元 雅代

  Faculty Of Pharmaceutical Sciences Fukuoka University

• 山内 辰郎

  Faculty Of Pharmaceutical Sciences Fukuoka University

• 八山 しづ子

  Faculty Of Pharmaceutical Sciences Fukuoka University

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