Studies on the Constituents of Aster scaber THUNB, IV. Structures of Four New Echinocystic Acid Glycosides Isolated from the Herb
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概要
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Four new echinocystic acid 3,28-O-bisdesmosides, scaberosides Ha, Hb_1,Hb_2 and Hc_1,were isolated as their methyl esters from the ground part of Aster scaber THUNB. (Compositae) along with foetidissimoside A and scaberoside A_2,and their structures were determined based on spectral and chemical evidence. These glycosides have a common prosapogenin structure, echinocystic acid-3-O-glucopyranosiduronic acid, and differ in the structures of the 28-O-linked sugar moieties.Scaberoside Ha_1 is a 28-[O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl] ester, Hb_1,a 28-[O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)-β-D-xylopyranosyl] ester, Hb_2,a 28-[O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)-β-D-xylopyranosyl] ester, and Hc_1,a 28-[O-β-D-xylopyranosyl-(1→3)-O-β-D-xylopyranosyl-(1→3)-[O-β-D-xylopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→2)-[O-α-L-rhamnopyranosyl-(1→3)]-β-D-xylopyranosyl] ester of the prosapogenin.
- 1993-04-15
著者
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長尾 常敦
福岡大
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岡部 光
Faculty Of Pharmaceutical Sciences Fukuoka University
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岩瀬 由紀子
福岡大学薬学部
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岡部 光
福岡大学
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Okabe Hikaru
福岡大学 薬学部
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田中 龍一郎
Faculty of Pharmaceutical Sciences, Setsunan University
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岩瀬 由紀子
Faculty of Pharmaceutical Sciences, Fukuoka University
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長尾 常敦
Faculty of Pharmaceutical Sciences, Fukuoka University
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田中 龍一郎
Faculty Of Pharmaceutical Sciences Fukuoka University
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