Synthesis and Optical Properties of 2,3-Dideoxy-D-erythro-hex-2-enopyranosyl Nucleosides (Nucleosides and Nucleotides. LXII)
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概要
- 論文の詳細を見る
Condensation of 3,4,6-tri-O-acetyl-D-glucal and trimethylsilylated nucleobases in the presence of stannic chloride or trimethylsilyl trifluoromethanesulfonate gave anomeric mixtures of 2,3-dideoxy-D-erythro-hex-2-enopyranosyl nucleosides. The signs of the circular dichroism (CD) spectra of the anomeric 2-hexenopyranosyl nucleosides are opposite to those of usual nucleosides or glucopyranosyl nucleosides. Other examples illustrating the contribution of an unsaturated bond in the sugar portion of nucleosides to the CD spectra are also presented.
- 公益社団法人日本薬学会の論文
- 1985-09-25
著者
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上田 亨
Faculty of Pharmaceutical Science, Hokkaido University
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上田 亨
Faculty Of Pharmaceutical Sciences Hokkaido University
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上田 亨
北海道大学薬学部
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渡部 伸一
Faculty Of Pharmaceutical Sciences Hokkaido University
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