Subterminal Hydroxylation of Ketoalkanes by Fungi

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概要

• 論文の詳細を見る

• Fusarium avenaceum f. sp. fabae IFO-7158 metabolized ketoalkanes and accumulated two or three monohydroxy forms from each ketoalkane. The positions for hydroxylation tended to shift to the ketonic group with an increase in the carbon number of the ketoalkane alkyl chain. In the cases of hexyl, heptyl and octyl groups, mainly the ω2 and ω3 positions were hydroxylated. For nonyl and undecyl groups, the substrates were converted into ω2-, ω3-, and ω4-derivatives and ω3-, ω4-, and ω5-derivatives, respectively. Subterminal hydroxylation of n-undecan-2-one was also carried out by Penicillium, Aspergillus, Trichoderma, and Cladosporium. Cleavage reactions of a C-C bond accompanied by subterminal hydroxylation of n-undecan-2-one and n-tridecan-2-one.

• 社団法人日本生物工学会の論文
• 1992-10-25

著者

• Yagi Takashi

  Research And Development Center Showa Sangyo Co. Ltd.

• HATANO TAKUSHI

  Department of Bioengineering, Faculty of Engineering, Fukuyama University

• FUKUI SAKUZO

  Department of Bioengineering, Faculty of Engineering, Fukuyama University

• Yagi T

  Showa Sangyo Co. Ltd. Funabashi Jpn

• Fukui F

  Showa Sangyo Co. Ltd. Ibaraki Jpn

• Fukui Fumio

  Fermentation Research Laboratories Sankyo Co. Ltd.

• YAGI TAKASHI

  R & D Center, Showa Sangyo Co., Ltd.,

• FUKUI FUMIO

  R & D Center, Showa Sangyo Co., Ltd.,

• Fukui Sakuzo

  Department Of Bioengineering Faculty Of Engineering Fukuyama University

• Hatano Takushi

  Department Of Bioengineering Faculty Of Engineering Fukuyama University

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