Mercuration of Quinoline N-Oxide
スポンサーリンク
概要
- 論文の詳細を見る
Mercurations of quinoline N-oxide with various reagents under different conditions were investigated using gas chromatographic analysis of the bromoquinolines derived from the reaction products. Mercuration in acetic acid or perchloric acid gave 8-mercurichloride as a main product and small amounts of 3-, 5-, 6- and 7-isomers. The reaction with mercuric sulfate without solvent gave all of the isomers, although the total yield was poor.
- 公益社団法人日本薬学会の論文
- 1969-05-25
著者
-
池川 信夫
Iwaki Meisei University
-
池川 信夫
Rikagaku Kenkyusho (the Institute Of Physical And Chemical Research)
-
星野 修
Rikagaku Kenkyusho The Institute Of Physical And Chemical Research
-
本間 靖
Organic Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.
-
本間 靖
Rikagaku Kenkyusho (The Institute of Physical and Chemical Research)
-
星野 修
Rikagaku Kenkyusho (the Institute Of Physical And Chemical Research):(present Address)faculty Of Pha
-
星野 修
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
関連論文
- Synthesis of 2-Phenylthiazolidine Derivatives as Cardiotonic Agents. IV. Modification of the Phenylpiperazino Moiety of 2-(Phenylpiperazino-alkoxyphenyl)thiazolidine-3-carbothloamides and the Corresponding Carboxamides(Medicinal Chemistry,Chemical)
- Synthesis of 2-Phenylthiazolidine Derivatives as Cardiotonic Agents. II. 2-(Phenylpiperazinoalkoxyphenyl)thiazolidine-3-thioearboxamides and the Corresponding Carboxamides(Medicinal Chemistry,Chemical)
- Synthesis of 2-Phenylthiazolidine Derivatives as Cardiotonic Agents. I. 2-Phenylthiazolidine-3-thiocarboxamides(Medicinal Chemistry,Chemical)
- Effect on Carbon Lengthening at the Side Chain Terminal of 1α, 25-Dihydroxyvitamin D_3 for Calcium Regulating Activity
- Studies on Antiallergic Agents. I. Phenyl-substituted Heterocycles with a 5-Tetrazolyl or N-(5-Tetrazolyl) carbamoyl Group
- Studies on Tetrahydroisoquinolines. XXV. A Synthesis of 4-Aryl-1,2,3,4-tetrahydroisoquinolines ; Total Synthesis of (±)-Cherylline
- 8-クロロモルフィナンジエノンおよび8-クロロホモモルフィナンジエノンの合成 (生物活性物質)
- Studies on Tetrahydroisoquinolines. XII. An Alternative Synthesis of (±)-Bracteoline, (±)-Isoboldine, (±)-N-Methyllaurotetanine, and Their Related Aporphines
- Studies on Tetrahydroisoquinolines. X. A Stereospecific Synthesis of (±)-Cataline
- A Novel Cyclononatriene System from N-Veratrylethanolamine-N-tosylate
- Chemistry of Cyclotriveratrylene. I. Formation of Cyclotriveratrylene from Veratrylamine N-Tosylates
- Ferricyanide Oxidation of dl-N-Methylisosalsoline and Its Methiodide
- Ferricyanide Oxidation of Corypalline and Its Methiodide
- 58 セレチウムアルカロイドの合成研究
- 21 ヒガンバナ科アルカロイド、(±)-リコリンの合成(口頭発表の部)
- Synthesis of N-Substituted C-Normorphinans and Their Pharmacological Properties
- Azabicycloalkanes as Analgetics. I. Synthesis of 1-Phenyl-6-azabicyclo [3,2,1] octane Derivatives
- Gas Chromatography of Triterpenes. I. Ursanane, Oleanane, and Lupane Groups
- Studies on Tetrahydroisoquinolines. XXVI. : A Biomimetic Synthesis of 5-Oxygenated 1,2,3,4-Tetrahydroisoquinolines
- Benzoyl Group Participation in Epoxide Ring Opening of 26-Benzoxy-24,25-epoxycholesterol Derivatives ; Reinvestigation of the Stereochemistry
- 19 モンタニン型アルカロイド、(±)-モンタニン、(±)-コクシニンの全合成(口頭発表の部)
- Studies on Tetrahydroisoquinolines. XXX. A Synthesis of Mixed Tetrahydroisoquinoline Dimers via p-Quinol Acetates
- Studies on Tetrahydroisoquinolines. XXIII. Reactions of (±)-7-Acetoxy-7-methoxy-1-(3,4-dimethoxy-or 3,4-methylenedioxybenzyl)-2-methyl-6-oxo-Δ^-hexahydroisoquinoline (o-Quinol Acetate)
- Studies on Tetrahydroisoquinolines. XXI. A Synthesis of (±)-1-Hydroxy-2-methoxyhomoproaporphine and Stereochemistry of 4-Oxygenated 1,2,3,4-Tetrahydroisoquinolines
- 77 リコリン関連化合物の合成研究
- 99(P20) ラジカル反応を利用する(+)-リコリンの合成研究(ポスター発表の部)
- 88 ラジカル反応を利用したモンタニン型アルカロイドの形式的全合成(ポスター発表の部)
- Azabicycloalkanes as Analgetics. II. An Improved Synthesis of 1-Phenyl-6-azabicyclo [3,2,1] octane Derivatives
- Studies on Tetrahydroisoquinolines. XXXVII. : A Synthesis of 3-Hydroxyaporphines and 3-Hydroxyhomoaporphines
- Mercuration of Quinoline N-Oxide
- Systematic Analysis of Steroids. VIII. Molecular Structure of C_ and C_ Steroid Derivatives and Retention Times in Gas Chromatography.
- Studies on the Plant Sterols and Triterpenes. II. Separation of Stigmasterol, β-Sitosterol and Campesterol, and about So-called "γ-Sitosterol."
- Gas Chromatography of Triterpenes. II. Hopane-Zeorinane and Onocerane Groups
- On Methyl-1-phenylnaphthalenes. II. The Gas Chromatography of Methyl-1-phenylnaphthalenes.
- Gas Chromatography of Stereoisomer of Ring System.
- On Cryptopimaric Acid and Neoisopimaric Acid
- Studies on Naphthyridines. V. Catalytic Reduction of Naphthyridines.
- Studies on Naphthyridines. IV. Infrared Spectra of Naphthyridines.
- Studies on Naphthyridines. III. Syntheses of 2,10-Diazaanthracene and 1,7-Naphthyridine.
- Studies on Naphthyridines. II. Synthesis of 2,7-Naphthyridine.
- Studies on Naphthyridines. I. Synthesis of 1,6-Naphthyridine.
- Revised Stereostructure for (+)-Roemecarine and Synthesis of (±)-, (+)-, and (-)-Roemercarine and (±)-Epiroemecarine
- Kinetic Resolution of (±)-4-Acyloxy-1,2,3,4-tetrahydro-6,7-dimethoxy-2-methylisopuinolines by Use of Immobilized Lipases in Organic Solvents
- Studies on Tetrahydroisoquinolines. XXXII. : Conversion of 7-Hydroxy-6-methoxytetrahydroisoquinolines to 6-Hydroxy-7-methoxytetrahydroisoquinolines
- A Synthesis of Seco-mesembrane Alkaloids, (±)-Joubertiamine, (±)-Joubertinamine, and (±)-Epijoubertinamine
- Studies on Tetrahydroisoquinolines. XXXI. : A synthesis of Tetrahydroisoquinoline Dimers by Intermolecular C-O Coupling
- Synthesis of Sceletium and Amaryllidaceae Alkaloids, (±)-Mesembrine and (±)-Dihydromaritidine, (±)-Epidihydromaritidine, (±)-Elwesine, and (±)-Epielwesine(Organic,Chemical)
- Studies on Tetrahydroisoquinolines. XXVIII. : Syntheses of (±)-N-Methyllaurotetanine, (±)-Cassythicine, (±)-9-Hydroxy-1,2,3,10-tetramethoxyaporphine, (±)-Dicentrine, and (±)-Thalicsimidine
- Studies on Tetrahydroisoquinolines. XXIV. A Synthesis of Dibenzo [c, f]-1-azabicyclo [3.3.1] nonanes and Dibenzo [d, g]-1-azabicyclo [4.3.1] decanes
- Studies on Tetrahydroisoquinolines. XXII. A Stereospecific Synthesis of (±)-Srilankine and (±)-Cataline
- Studies on Tetrahydroisoquinolines. XX. A Novel Synthesis of 8-Aryl-1,2,3,4-tetrahydroisoquinolines
- Studies on Tetrahydroisoquinolines. XIX. Synthesis of (±)-Isothebaine, (±)-1-Hydroxy-2,9-dimethoxy-, (±)-1-Hydroxy-2,10-dimethoxy-, and (±)-2,10-Dimethoxy-aporphines, (±)-2,6-Dimethoxyhomomorphinandienone, and (±)-1-Hydroxy-2,10-dimethoxyhomoaporphine
- Studies on Tetrahydroisoquinolines. XVII. A Synthesis of 8-Halo-1,2,3,4-tetrahydroisoquinolines
- Regioselective Synthesis of 14-Membered Biaryl Ethers : Total Synthesis of RA-VII and Deoxybouvardin
- A Cyclization of β-Arylethylisocyanates to 3,4-Dihydroisocarbostyrils
- アポルフィンアルカロイド合成の二,三の話題
- Studies on Tetrahydroisoquinolines. VII. Synthesis of Homoaporphine via a p-Quinol Acetate ; Total Synthesis of (±)-Kreysigine
- Studies on Tetrahydroisoquinolines. VI. Synthesis of (±)-Thaliporphine and (±)-Glaucine via a p-Quinol Acetate
- Studies on Tetrahydroisoquinolines. I. Formation and Acid-Catalyzed Rearrangement of 10-Acetoxy-6-methoxy-2-methyl-7-oxo-Δ^-hexahydroisoquinolines
- A Novel Rearrangement of a Quinol Acetate
- Resin酸における2,3の研究
- エキソオレフィンを有するエンイン化合物の Pauson-Khand 反応とリコポジウムアルカロイド, magellanine の全合成への応用
- 86(P-20) リコポジウムアルカロイド、magellanineの合成研究(ポスター発表の部)
- 121(P-58) エキソメチレン化合物の分子内Pauson-Khand反応とリコポジウムアルカロイド、magellanine合成への応用(ポスター発表の部)
- Studies on Tetrahydroisoquinolines. XVI. Preparation of 2-Hydroxyaporphines via O-Quinol Acetates
- Organic Photochemistry. V. Dethioacetalization by Photolysis in the Presence of Molecular Oxygen
- A Novel Synthesis of Aporphine Alkaloids via o-Quinol Acetates
- Studies on Tetrahydroisoquinolines. VIII. Lead Tetraacetate Oxidation of 1,2,3,4-Tetrahydro-6-hydroxy-7-methoxy-2-methylisoquinoline and Its 1-Substituted Derivatives
- Studies on Tetrahydroisoquinolines. XI. A Facile Synthesis of (±)-Aporphines via p-Quinol Acetates
- Studies on Tetrahydroisoquinolines. IX. The Synthesis of (±)-Domesticine and a Related (±)-Homoaporphine via p-Quinol Acetates
- 34 キノールアセタートを経由するイソキノリンアルカロイドの合成
- A Further Investigation on Oxidative Coupling of dl-2-Methylisosalsoline
- Configuration at the C-23 Position of 23-Hydroxy- and 23,25-Dihydroxycholesterols
- Studies on Tetrahydroisoquinolines. V. Synthesis of 4-Alkyl-7-hydroxy-6-methoxy-2-methyl-1,2,3,4-tetrahydroisoquinolines
- Organic Photochemistry. III. Photo-reductive Cleavage of p-Toluenesulfonamides
- Organic Photochemistry. II. Tetrahydroisoquinolines from Their N-Tosylates
- Organic Photochemistry. I. 3,4-Dihydroisoquinolines from Tetrahydroisoquinoline N-Tosylates
- New Inter-relationship of Abietic Acid and Agathic Acid
- Diterpenoids. XII. Catalytic Hydrogenation of Δ^-and 6-Enol Acetoxyhydrofluorene Derivatives. A Synthesis of Hydrofluorene Derivatives (cis-A/B-Ring Fusion (α C_5-H))
- Diterpenoids. XI. A Synthesis of Hydrofluorene Derivatives (trans-A/B-Ring Fusion (β C_5-H))
- Diterpenoids. X. A Synthesis of c-Homohydrofluorene
- 39 Diterpeneに於ける骨格の変換
- 12 Abietic AcidよりHydrofluorene誘導体への変換
- Transformation of Abietic Acid to Hydrofluorene Derivative (Part II)
- モンタニン型ヒガンバナ科アルカロイド, (±) -モンタニン, (±) -コクシニン, (±) -パンクラシンおよび (±) -ブルンスビジンの全合成
- Studies on Tetrahydroisoquinolines. IV. Synthesis of 4-Alkyl (phenyl) amino-7-hydroxy-6-methoxy-2-methyl-1,2,3,4-tetrahydroisoquinolines
- Studies on Tetrahydroisoquinolines. III. Synthesis of 4-Alkoxy- or Alkyl (phenyl)-mercapto-7-hydroxy-6-methoxy-2-methyl-1,2,3,4-tetrahydroisoquinolines
- Studies on Tetrahydroisoquinolines. II. An Acid-Catalysed Alcoholysis of 10-Acetoxy-6-methoxy-2-methyl-7-oxo-Δ^-hexahydroisoquinoline (p-Quinol Acetate)