Organic Photochemistry. V. Dethioacetalization by Photolysis in the Presence of Molecular Oxygen
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概要
- 論文の詳細を見る
Photolysis (a 200 W high pressure mercury lamp) under oxygen stream of ethylene dithioacetals of 5,6-dimethoxy-α-indanone, α-and β-indanone, α-tetralone, 5α-and 5β-cholestan-3-ones, cholest-4-en-3-one, and cyclohexanone in an appropriate solvent (nhexane, ethanol or benzene) was carried out to give the parent ketones. Ethylene dithioacetal of cholest-5-en-3-one on photolysis followed by NaBH_4 reduction gave cholest-4-en-3β-o1,showing photo-induced isomerization of the double bond.
- 公益社団法人日本薬学会の論文
- 1979-02-25
著者
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星野 修
東京理科大学薬学部
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星野 修
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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梅澤 文輔
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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沢木 正平
東京理科大薬
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梅澤 文輔
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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沢木 正平
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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星野 修
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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