Studies on Tetrahydroisoquinolines. XXII. A Stereospecific Synthesis of (±)-Srilankine and (±)-Cataline
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概要
- 論文の詳細を見る
Lead tetraacetate oxidation of (±)-predicentrine (4) in acetic acid and in CH_2Cl_2 gave (±)-4-O-acetylsrilankine (11) and the o-quinol acetate (6), respectively. The latter (6) was transformed into (±)-O, O-diacetylsrilankine (13) under Thiele's conditions. Hydrolysis of 11 or 13 afforded (±)-srilankine (1), methylation of which yielded (±)-cataline (2).
- 公益社団法人日本薬学会の論文
- 1984-10-25
著者
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星野 修
東京理科大学薬学部
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原 博
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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原 博
東京理科大学薬学部
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星野 修
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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梅澤 文輔
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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梅澤 文輔
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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橋本 文章
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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原 博
東京理大 薬
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星野 修
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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橋本 文章
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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