m-ジニトロベンゼン誘導体とシアン化アルカリの呈色反応機構(第3報) : 2,4-ジニトロフェノールとシアン化カリウムの反応生成物
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概要
- 論文の詳細を見る
The reaction products (I, II, III and IV) were separated as their methyl ethers from the color reaction mixture of 2,4-dinitrophenol with potassium cyanide in aqueous solution, and their chemical structures were elucidated mainly by their spectral properties. III and IV, nitro-substituted 2,3-dihydro-3-oxo-1H-indazoles, were the main coloring matters in this reaction, and III was found to be formed through the intermediates, I and II (Chart 1). This fact confirmed the previously postulated mechanism of the color reaction between m-dinitrobenzene derivatives and alkali cyanide.
- 公益社団法人日本薬学会の論文
- 1972-05-25
著者
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大倉 洋甫
Faculty Of Pharmaceutical Sciences Kyushu University
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大倉 洋甫
九州大学薬学部
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上田 陽
九州大学薬学部
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百瀬 勉
Faculty Of Pharmaceutical Sciences Kyushu University
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塩田 順造
九州大学薬学部
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百瀬 勉
九州大学薬学部
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