Insight into the Cyclization of 6-Octen-1-als with Rhodium(I) Complex
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概要
- 論文の詳細を見る
Cyclization of 6-octen-1-als with Rh(I) (Wilkinson) complex was examined. In all cases with methyl substituents at the C_2- or C_3-position, a mixture of cis- and trans-cyclohexanol derivatives was obtained, but 7-methyl-6-octen-1-al without any substituents instead underwent a decarbonylation reaction. 4-Oxa-analogues also afforded a similar result. In Rh(I)-catalyzed cyclization, the formation of cis-cyclohexanols is in remarkable contrast to Lewis acid-catalyzed cyclization to afford the trans products.
- 社団法人日本薬学会の論文
- 1989-08-25
著者
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酒井 浄
Faculty of Pharmaceutical Sciences, Kyushu University
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酒井 浄
Faculty Of Pharmaceutical Sciences Kyushu University
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舟越 和久
九大薬
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舟越 和久
Faculty of Pharmaceutical Sciences, Kyushu University
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東郷 暢子
Faculty of pharmaceutical Sciences, Kyushu University
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古賀 一郎
Faculty of Pharmaceutical Sciences, Kyushu University
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舟越 和久
Faculty Of Pharmaceutical Sciences Kyushu University
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東郷 暢子
Faculty Of Pharmaceutical Sciences Kyushu University
-
古賀 一郎
Faculty Of Pharmaceutical Sciences Kyushu University
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