Studies on Tertiary Amine Oxides LXXXII. : The Reaction of 1-Oxido-4(or 2)-pyridinediazonium Tetrafluoroborate with Olefins in the Presence of Palladium Complex

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概要

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• 1-Oxido-4-pyridinediazonium tetrafluoroborate (4-PFB) reacts with olefins (cyclopentene, styrene, ethyl acrylate, indene, cyclohexene, cyclooctene, 1-octene and 1-dodecene) in the presence of tris(dibenzylideneacetone)dipalladium to afford the corresponding alkenylated products (1,2,3,4,5,6,7 and 8) in good yields.1,2,3,5-Oxatriazolo[5,4-α]pyridinium tetrafluoroborate (2-PFB) also reacts with cyclopentene and styrene to give 2-cyclopentenylpyridine 1-oxides (13 and 14) and (E)-2-(α-styryl)pyridine 1-oxide (15), respectively, in low yields.

• 公益社団法人日本薬学会の論文
• 1986-01-25

著者

• 佐伯 清太郎

  Faculty of Pharmaceutical Sciences, Kyushu University

• 舟越 和久

  Faculty of Pharmaceutical Sciences, Kyushu University

• 近藤 幸子

  Faculty Of Pharmaceutical Sciences Kyushu University

• 舟越 和久

  Faculty Of Pharmaceutical Sciences Kyushu University

• 浜名 政和

  Faculty of Pharmaceutical Sciences, Kyushu University

• 佐伯 清太郎

  Faculty Of Pharmaceutical Sciences Kyushu University

• 浜名 政和

  Faculty Of Pharmaceutical Sciences Kyushu University

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