Biosynthesis of Bisorbicillinoid in Trichoderma sp. USF-2690 ; Evidence for the Biosynthetic Pathway, via Sorbicillinol, of Sorbicillin, Bisorbicillinol, Bisorbibutenolide, and Bisorbicillinolide(Organic Chemistry)
スポンサーリンク
概要
- 論文の詳細を見る
An incorporation study of [1-^<13>C] and [1, 2-^<13>C_2] labeled sodium acetates into sorbicillinol 1 established a ring closure system between C-1 and C-6 and the positions that were oxidized and/or methylated on a hexaketide chain. Subsequent investigations, using ^<13>C-labeled 1 prepared from [1-^<13>C] labeled sodium acetate, clearly demonstrated that both bisorbicillinol 2 and sorbicillin 6 incorporated ^<13>C-labeled 1 into their carbon skeletons. ^<13>C-labeled bisorbicillinols 2 derived from [1-^<13>C]- and [2-^<13>C]-labeled sodium acetates clearly indicate that these were on the biosynthetic route from 1 to bisorbibutenolide (bislongiquinolide) 3 and bisorbicillinolide 4 via 2 as a branching point in the fungus.
- 社団法人日本農芸化学会の論文
- 2002-10-23
著者
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ABE Naoki
Laboratory of Applied Microbiology, School of Food and Nutritional Sciences, University of Shizuoka
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HIROTA Akira
Laboratory of Applied Microbiology, School of Food and Nutritional Sciences, University of Shizuoka
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Abe N
Faculty Of Applied Bio-science Tokyo University Of Agriculture
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Abe Naoki
School Of Food And Nutritional Sciences University Of Shizuoka:(present Address)department Of Nutrit
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Hirota Akira
School Of Food And Nutritional Sciences Univ. Of Shizuoka
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Hirota A
Department Of Agricultural Chemistry University Of Osaka Prefecture
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Hirota Akira
Department Of Agricultural Chemistry College Of Agriculture University Of Osaka Prefecture
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Yamamoto K
Laboratory Of Insect Genetic Resources Faculty Of Agriculture Kyushu University
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Yamamoto K
Kyushu Univ. Fukuoka
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Arakawa T
Allaiance Protein Laboratories
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ARAKAWA Tadaharu
School of Food and Nutritional Sciences, University of Shizuoka
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YAMAMOTO Kazunobu
School of Food and Nutritional Sciences, University of Shizuoka
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Abe N
Laboratory Of Applied Microbiology School Of Food And Nutritional Sciences University Of Shizuoka
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Abe Naoki
School Of Food And Nutritional Sciences University Of Shizuoka
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Arakawa Tadaharu
School Of Food And Nutritional Sciences University Of Shizuoka
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