The crystal and molecular structure of 12-bromo(2.2)(2.2)triple-layered paracyclophane.

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概要

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• The molecular structure of 12-bromo[2.2][2.2]paracyclophane has been determined by means of X-ray diffraction. The crystal is orthorhombic, space group <I>Pbcn</I>, <I>a</I>=12.768(1), <I>b</I>=11.515(1), <I>c</I>=13.074(1) Å, <I>Z</I>=4. The structure was solved by the heavy-atom method, and refined anisotropically by the block-diagonal leastsquares procedure; <I>R</I>=0.062. The Br–C···C–H axis of the central benzene ring lies on a crystallographic two-fold axis. The outer benzene rings take a boat form, and the central benzene ring is twisted.

• 公益社団法人 日本化学会の論文

著者

• Miki Kunio

  Department Of Chemistry Graduate School Of Science Kyoto University

• Misumi Soichi

  The Institute Of Scientific And Industrial Research Osaka University

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Koizumi Yosuke

  The Institute of Scientific and Industrial Research, Osaka University

• Toyoda Toshihiro

  The Institute of Scientific and Industrial Research, Osaka University

• Miki Kunio

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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