Layered compounds. XXXV. Syntheses of triple-layered metaparacyclophanes.
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概要
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Six triple-layered [2.2]metaparacyclophanes have been prepared using general synthetic methods such as the Stevens rearrangement-Raney nickel desulfurization method, pyrolysis of bissulfone, and photo-induced desulfurization. The pyrolysis of bissulfone has turned out to be the most useful and convenient method for preparation of the intermediate double-layered [2.2]metaparacyclophanes because of simple experimental process and excellent yields. The unexpected formation of compound <B>9</B> during the photo-induced desulfurization of <B>7</B> was explained by a unique skeletal rearrangement of the intermediate <B>8</B> on irradiation.
- 公益社団法人 日本化学会の論文
著者
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Sakata Yoshiteru
The Institute Of Science And Industrial Research Osaka University
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Misumi Soichi
The Institute Of Scientific And Industrial Research Osaka University
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Otsubo Tetsuo
The Institute of Scientific and Industrial Research, Osaka University
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Kannen Naoki
The Institute of Scientific and Industrial Research, Osaka University
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