Flash pyrolysis of selenides. Syntheses of bibenzyls, olefins, and related compounds.
スポンサーリンク
概要
- 論文の詳細を見る
Pyrolyses of a series of selenides and diselenides were studied. Selenides and diselenides bound with an active methylene group like benzyl gave a variety of substituted bibenzyls and related ethane derivatives in high yields. Other diselenides were easily caused to cleave to give various aromatic and aliphatic olefins in good yields together with elemental selenium. Lepidopterene, [2.2]paracyclophane, and benzocyclobutene were prepared by thermal cleavage of their corresponding phenylselenomethyl-substituted compounds as an application of the pyrolysis concerned.
- 公益社団法人 日本化学会の論文
著者
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Ogura Fumio
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Otsubo Tetsuo
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Sakata Yoshiteru
The Institute Of Science And Industrial Research Osaka University
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MISUMI Soichi
The Institute of Scientific and Industrial Research, Osaka University
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Misumi Soichi
The Institute Of Scientific And Industrial Research Osaka University
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Yamaguchi Hachiro
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Higuchi Hiroyuki
The Institute Of Scientific And Industrial Research Osaka University
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