The synthesis of 2,7-bis(dimethylamino)pyrene and -tetrahydropyrene and the electrical conductivities of their complexes.
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概要
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New π-donors containing a pyrene or a tetrahydropyrene ring were synthesized by means of a unique transannular reaction of the corresponding [2.2]metacylcophane derivatives. The CT complexes of these donors with a series of TCNQ derivatives different in electron affinity were prepared, and their electrical conductivities on single crystals were measured. The highest conductivity (0.36 Ω<SUP>−1</SUP> cm<SUP>−1</SUP>) was that of the tetrahydropyrene derivative-TCNQ complex. It was reconfirmed that the partial charge-transfer from a donor to an acceptor is very important for high conductivity.
- 公益社団法人 日本化学会の論文
著者
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Sakata Yoshiteru
The Institute Of Science And Industrial Research Osaka University
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Misumi Soichi
The Institute Of Scientific And Industrial Research Osaka University
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Inokuchi Hiroo
The Institute For Solid State Physics The University Of Tokyo
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Saito Gunzi
The Institute for Molecular Science
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Ueda Naomi
The Institute of Scientific and Industrial Research, Osaka University
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Natsume Bunji
The Institute of Scientific and Industrial Research, Osaka University
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Yanagiuchi Kazumi
The Institute of Scientific and Industrial Research, Osaka University
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Enoki Toshiaki
The Institute for Molecular Science
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Inokuchi Hiroo
The Institute for Molecular Science
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