Novel Radical Salt Polymers as Hydrogenation Catalyst of α-Olefins
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概要
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Novel polymeric radical salts prepared by inserting alkali-metals into semi-conductive polymers derived from poly(tetrahalophenylene sulfides) were found to be effective hydrogenation catalyst for α-olefins; their activity trends as to the sort of alkali-metal and halogen of the matrix polymer were Cs>K>Na and F>Cl>Br respectively. The catalyst also showed an activity for the <I>cis-trans</I> isomerization of hex-2-ene which was proportional to that for the hydrogenation. The activities of the catalyst were discussed in terms of its steric confinement.
- 公益社団法人 日本化学会の論文
著者
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Inokuchi Hiroo
The Institute For Solid State Physics The University Of Tokyo
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Murano Kentaro
The Institute for Solid State Physics, The University of Tokyo
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Kawazura Hiroshi
Research Laboratory, Japan Synthetic Rubber Co., Ltd.
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Yamamoto Yoshiro
Research Laboratory, Japan Synthetic Rubber Co., Ltd.
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Ohmori Toshio
Research Laboratory, Japan Synthetic Rubber Co., Ltd.
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Ohmori Toshio
Research Laboratory, Japan Synthetic Rubber Co.
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Inokuchi Hiroo
The Institute for Molecular Science
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Kawazura Hiroshi
Research Laboratory, Japan Synthetic Rubber Co.
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