Flash Pyrolysis of Selenides : Syntheses of Bibenzyls, Olefins, and Related Compounds

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概要

• 論文の詳細を見る

• Pyrolyses of a series of selenides and diselenides were studied. Selenides and diselenides bound with an active methylene group like benzyl gave a variety of substituted bibenzyls and related ethane derivatives in high yields. Other diselenides were easily caused to cleave to give various aromatic and aliphatic olefins in good yields together with elemental selenium. Lepidopterene, [2.2]paracyclophane, and benzocyclobutene were prepared by thermal cleavage of their corresponding phenylselenomethyl-substituted compounds as an application of the pyrolysis concerned.

• 福山大学の論文

著者

• OTSUBO Tetsuo

  Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University

• OGURA Fumio

  Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University

• SAKATA Yoshiteru

  The Institute of Scientific and Industrial Research, Osaka University

• 山口 八郎

  福山大学薬学部

• Ogura Fumio

  Department Of Applied Chemistry Faculty Of Engineering Hiroshima University

• Otsubo Tetsuo

  Department Of Applied Chemistry Faculty Of Engineering Hiroshima University

• Sakata Yoshiteru

  The Institute Of Science And Industrial Research Osaka University

• HIGUCHI Hiroyuki

  The Institute of Scientific and Industrial Research, Osaka University

• 山口 八郎

  Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

• MISUMI Soichi

  The Institute of Scientific and Industrial Research, Osaka University

• Misumi Soichi

  The Institute Of Scientific And Industrial Research Osaka University

• Higuchi Hiroyuki

  The Institute Of Scientific And Industrial Research Osaka University

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