Synthesis, structure, and properties of triple-layered [2.2][2.2]naphthalenophane.
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概要
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The title compound was synthesized in a similar manner to a simple access to triple-layered [2.2][2.2]paracyclophane. Its structure was elucidated by X-ray crystallographic analysis. The outer naphthalene rings are bent into a boat form and the inner naphthalene ring is bent into a twist form. These naphthalenes are stacked in layers within van der Waals contact. Therefore, there is a strong transannular π-electronic interaction between them, which brings about characteristic bathochromism, hyperchromism, and broadening in the electronic spectrum. These effects are more prominent than those of the double-layered homologue.
- 公益社団法人 日本化学会の論文
著者
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Aso Yoshio
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Ogura Fumio
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Otsubo Tetsuo
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Tanaka Jiro
Department Of Biomaterials Okayama University Graduate School Of Medicine Dentistry And Pharmaceutic
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Kawamoto Atsushi
Department of Biology, Faculty of Science, Chiba University
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Aso Yoshio
Department of Applied Chemistry, Faculty of Engineering, Hiroshima University
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Misumi Soichi
Institute of Scientific and Industrial Research, Osaka University
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