The crystal and molecular structure of 1:2 molecular complex of 1,4-diazabicyclo[2.2.2]octane(DABCO) with p-cresol.

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概要

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• X-Ray crystal structure analysis of the title compound is described. C<SUB>6</SUB>H<SUB>12</SUB>N<SUB>2</SUB>,2C<SUB>7</SUB>H<SUB>8</SUB>O, <I>F</I>. <I>W</I>. 328.5, monoclinic, space group <I>C</I>2⁄<I>c</I>, <I>a</I>=18.494(1), <I>b</I>=9.250(1), <I>c</I>=11.414(1) Å, β=103.67(1)°, <I>V</I>=1897.4(3) Å<SUP>3</SUP>, <I>D</I><SUB>c</SUB>=1.150 g cm<SUP>−3</SUP> for <I>Z</I>=4. The DABCO molecule in the crystal is bound to two <I>p</I>-cresol molecules by the strong O–H···N hydrogen bonds, and the crystal is composed of <I>p</I>-cresol···DABCO···<I>p</I>-cresol complex units.

• 公益社団法人 日本化学会の論文

著者

• Yasui Masanori

  Department Of Applied Physics And Chemistry The University Of Electro-communications

• Toda Fumio

  Department Of Applied Chemistry Faculty Of Engineering Ehime University

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Harada Shigeharu

  Department Of Applied Biology Kyoto Institute Of Technology

• Tanaka Koichi

  Department Of Anatomy School Of Medicine Chiba University

• Takama Masaaki

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• TANAKA Koichi

  Department of Anatomy and Cell Biology, Hyogo College of Medicine, 1–1 Mukogawa-cho, Nishinomiya, Hyogo 663–8501, Japan

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