Crystal and molecular structure of the crystalline host-guest complex between (R)-(+)-2,2'-dihydroxy-1,1'-binaphthyl and (S)-(-)-(ethyl m-tolyl selenoxide).

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概要

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• The crystal and molecular structure of the title complex was determined by X-ray method. The absolute configuration of the host (+)-2,2′-dihydroxy-1,1′-binaphthyl (<B>1</B>) was determined to be <I>R</I> and the guest (−)-(ethyl <I>m</I>-tolyl selenoxide) (<B>2</B>) to be <I>S</I>. Two Se–C and one S-O bond lengths are 1.926(7), 1.970(8), and 1.677(5) Å, respectively, and the arrangement around Se atom is roughly tetrahedral. There are O(guest)···HO(host)OH···O(guest) hydrogen bonds between the host and the guest molecules.

• 公益社団法人 日本化学会の論文

著者

• Toda Fumio

  Department Of Applied Chemistry Faculty Of Engineering Ehime University

• Mori Koji

  Department Of Applied Physics University Of Miyazaki

• Tanaka Naoki

  Department Of Bio-molecular Engineering Kyoto Institute Of Technology

• FUJIWARA Takaji

  Department of Chemistry, Faculty of Science, Shimane University

• FUJIWARA Takaji

  Department of Information Science, Faculty of Science, Shimane University

• Ooshita Ryuzou

  Department of Information Science, Faculty of Science, Shimane University

• Hino Ryoji

  Department of Information Science, Faculty of Science, Shimane University

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