The crystal and molecular structure of 2:2 complex of 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol (DD) with 1-methyl-2-(3-pyridyl)pyrrolidine (nicotine).

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概要

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• X-Ray crystal structure analysis of the title complex is described. 2(C<SUB>30</SUB>H<SUB>22</SUB>O<SUB>2</SUB>),2(C<SUB>10</SUB>H<SUB>14</SUB>N<SUB>2</SUB>), <I>F</I>.<I>W</I>. 1153.5, monoclinic, space group <I>P</I>2<SUB>1</SUB>, <I>a</I>=28.913(2), <I>b</I>=12.353(1), <I>c</I>=9.340(1) Å, β=98.20(1)°, <I>V</I>=3301.7(6) Å<SUP>3</SUP>, <I>D</I><SUB>c</SUB>=1.16 g cm<SUP>−3</SUP> for <I>Z</I>=2. Two DD molceules are bound by two nicotine by four O–H···N hydrogen bonds to form a 2:2 complex. The crystal consists of these asymmetric 2:2 complexes.

• 公益社団法人 日本化学会の論文

著者

• Toda Fumio

  Department Of Applied Chemistry Faculty Of Engineering Ehime University

• Mori Koji

  Department Of Applied Physics University Of Miyazaki

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Harada Shigeharu

  Department Of Applied Biology Kyoto Institute Of Technology

• Toda Mari

  Department Of Educational Psychology Hokkaido University Of Education

• Fukawa Ken-ichi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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