Crystal and Molecular Structure of Di-μ-chloro-bis(π-1-ethoxycarbonyl-2-hydroxyallyl)dipalladium(II)

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概要

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• The crystal and molecular structures of di-μ-chloro-bis-(π- 1-ethoxycarbonyl-2-hydroxyallyl)-dipalladium, (C<SUB>6</SUB>H<SUB>9</SUB>O<SUB>3</SUB>PdC<U>l</U>)<SUB>2</SUB> have been determined from the three-dimensional data. The crystals are triclinic; space group <I>P</I>l; with one dimeric molecule per unit-cell; <I>a</I>=4.80, <I>b</I>=10.31, <I>c</I>=10.64 Å, α=117.4, β=102.3, and γ=84.1°. The final discrepancy index is 14.0% for 1208 reflections. The two palladium atoms are joined by two chlorine bridges to form a square planar arrangement. The molecule possesses a center of symmetry which coincides with a crystallographic center of symmetry in the crystal; the overall coordination scheme of the palladium atom is similar to that established for the π-allyl palladium chloride dimer. The dihedral angle between the plane of four atoms [Pd, Pd′, Cl, and Cl′] and the π-allyl plane is 108. There are intermolecular hydrogen-bonds between the enolic hydroxyl group of one molecule and the carbonyl-group of the other molecule related by the center of symmetry.

• 公益社団法人 日本化学会の論文

著者

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Yasuoka Noritake

  Department Of Life Science Faculty Of Science Himeji Institute Of Technology

• Oda Kunio

  Department Of Internal Medicine Naruwa Hospital

• Kakudo Masao

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Ueki Tatzuo

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yasuoka Noritake

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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