The crystal and molecular structure of (acetylacetonato)-(diacetylmethyl)(diethylamine)palladium(II).

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概要

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• The molecular structure of [Pd(acac)<SUB>2</SUB>(NHEt<SUB>2</SUB>)] was determined by means of X-ray diffraction. The crystal belongs to the monoclinic system: <I>a</I>=14.166(1), <I>b</I>=8.209(1), <I>c</I>=14.764(2) Å, β=100.75(1)°, space group P2<SUB>1</SUB>/n, with <I>Z</I>=4. The structure was solved by the heavy-atom method and refined anisotropically by the least-squares procedure; <I>R</I>=0.067 for 3149 non-zero reflections. The geometry around the Pd atom is square-planar: one of the two (acac) ligands coordinates to the Pd atom by <I>O</I>,<I>O</I>′-chelation, and the other, by σ-bonding of the γ-carbon atom, while the diethylamine occupies the fourth coordination site. A weak intramolecular N–H···O hydrogen bond [2.962(10) Å] is observed.

• 公益社団法人 日本化学会の論文

著者

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Tanaka Nobuo

  Department Of Agro-environmental Sciences Graduate School Of Bioresource And Bioenvironmental Scienc

• Miki Kunio

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Kurokawa Takahiro

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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