The crystal and molecular structures of 4-ethyl-3,5-bis(phenylimino)-1,2,4-dithiazolidine and 2-ethyl-4-phenyl-5-phenylimino-1,2,4-thiadiazolidin-3-thione.

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概要

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• The molecular structures of title compounds, two of the three isomeric products in the reaction of 2-ethyl-3-phenyloxaziridine with phenyl isothiocyanate, have been determined by means of X-ray diffraction. 4-Ethyl-3,5-bis(phenylimino)-1,2,4-dithiazolidine (<B>6b</B>), orthorhombic, space group <I>Pcab</I>, <I>a</I>=27.171(1), <I>b</I>=10.213(2), <I>c</I>=11.421(1) Å, <I>Z</I>=8; 2-Ethyl-4-phenyl-5-phenylimino-1,2,4-thiadiazolidin-3-thione (<B>8b</B>), monoclinic, space group <I>P</I>2<SUB>1</SUB>⁄<I>n</I>, <I>a</I>=9.278(1), <I>b</I>=27.525(3), <I>c</I>=5.826(1) Å, β=92.74(1)°, <I>Z</I>=4. Both structures were solved by the heavy atom method, and refined anisotropically by the block-diagonal least-squares procedure (<I>R</I>=0.066 and 0.060, respectively). The results corrected the reaction scheme proposed for the reaction of <I>N</I>-alkyloxaziridine with phenyl isothiacyanate.

• 公益社団法人 日本化学会の論文

著者

• Komatsu Mitsuo

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Ohshiro Yoshiki

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Yasuoka Noritake

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Agawa Toshio

  Department of Petroleum Chemistry, Faculty of Engineering, Osaka University

• Kuriyama Mineo

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Agawa Toshio

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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