Lewis acid mediated reaction of trimethylstyrylsilanes with thioacetal derivatives.
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概要
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Treatment of trimethylstyrylsilanes with 1-ethoxy-1-(phenylthio)ethane or 2-ethoxy-1,3-dithiolane in the presence of Lewis acid gives the corresponding (<I>E</I>)-allyl sulfide or (<I>E</I>)-2-styryl-1,3-dithiolane, respectively. In both cases, a carbon-oxygen bond of thioacetal derivatives is cleaved selectively.
- 公益社団法人 日本化学会の論文
著者
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Ohshiro Yoshiki
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Hirao Toshikazu
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Agawa Toshio
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Kohno Shuichiro
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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