C,O-chelates of the trifluoroacetylacetonate dianion with palladium(II). Molecular structure of (Pd(tfac(2-)-C,O)(PPh3)(2,6-Me2-py))
スポンサーリンク
概要
- 論文の詳細を見る
Reactions of bis(trifluoroacetylacetonato)palladium(II), [Pd(tfac)<SUB>2</SUB>], with tertiary phosphines followed by pyridine or its derivatives afforded a series of the [Pd(tfac(2–)-<I>C</I>,<I>O</I>)LL′]-type complexes which contain a C,O-chelating trifluoroacetylacetonate dianion and a couple of tertiary phosphine and/or heterocyclic nitrogen base ligands (L and L′). Their structures in solution were studied by <SUP>1</SUP>H, <SUP>13</SUP>C, <SUP>19</SUP>F, and <SUP>31</SUP>P NMR spectroscopy and the molecular structure in a crystal of [Pd(tfac(2–)-<I>C</I>,<I>O</I>)(PPh<SUB>3</SUB>)(2,6-Me<SUB>2</SUB>-py)]·C<SUB>6</SUB>H<SUB>6</SUB> containing triphenylphosphine and 2,6-dimethylpyridine as L and L′ was determined by means of X-ray diffraction.
- 公益社団法人 日本化学会の論文
著者
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Nakamura Yukio
Department Of Biotechnology Faculty Of Agriculture Gifu University
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Okeya Seichi
Faculty Of Education Wakayama University
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Kawaguchi Shinichi
Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University
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Kanehisa Nobuko
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Kasai Nobutami
Department Of Applied Biological Science Tokyo University Of Science
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Miki Kunio
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Kawakita Yasuo
Faculty of Education, Wakayama University
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Matsumoto Shinichi
Department of Chemistry, Faculty of Science, Osaka City University
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