Some palladium(II) complexes containing both the O-unidentate .BETA.-diketonato and 2-,3-, or 4-pyridyl ligands. Dynamic behaviors of trans-(Pd(.BETA.-dik-O)(C5H3(6-Cl)N-C2)(PEt3)2) in solution.
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概要
- 論文の詳細を見る
Palladium(II) complexes of the [Pd(β-dik-<I>O</I>)(pyridyl)(PEt<SUB>3</SUB>)<SUB>2</SUB>] type containing an <I>O</I>-unidentate acetylacetonate, trifluoroacetylacetonate, or hexafluoroacetylacetonate anion and a 2-, 3-, 4-pyridyl or 6-chloro-2-pyridyl group as ligands were prepared and characterized mainly by <SUP>1</SUP>H and <SUP>13</SUP>C NMR spectroscopy. The acetylacetonate and hexafluoroacetylacetonate ligands in the [Pd(β-dik-<I>O</I>)(C<SUB>5</SUB>H<SUB>3</SUB>(6-Cl)N-<I>C</I><SUP>2</SUP>)(PEt<SUB>3</SUB>)<SUB>2</SUB>] complexes undergo the head-to-tail donor-atom exchange reaction, to which an intramolecular mechanism is proposed.
- 公益社団法人 日本化学会の論文
著者
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Isobe Kiyoshi
Department Of Agricultural Chemistry Faculty Of Agriculture Shizuoka University
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Okeya Seichi
Faculty Of Education Wakayama University
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Kawaguchi Shinichi
Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University
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Tanaka Hiroshi
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences Hoshi University
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