Trimethylenediamine Complexes. II. Some <I>cis-trans</I> Isomeric Pairs of Diacidobis(trimethylenediamine)cobalt(III) Complexes

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概要

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• Isomeric pairs of <I>cis</I>- and <I>trans</I>-dinitro-, diisothiocyanato- and cyanosulfito-bis(trimethylenediamine)cobalt(III) complexes, and <I>cis</I>-nitronitritobis(trimethylenediamine)cobalt(III) nitrite were synthesized. Their electronic and infrared spectra were compared with each other to assign their structures. The <I>cis</I>-diisothiocyanatobis(trimethylenediamine)cobalt (III) complex was resolved into optically active isomers by means of potassium antimony(III) (+)-tartrate. The circular dichroism spectra of this dissymmetric complex were measured and discussed in relation to its absolute configuration which was recently determined by X-ray analysis.

• 公益社団法人 日本化学会の論文

著者

• Kawaguchi Shinichi

  Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University

• Kawaguchi Hiroshi

  Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University

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