Trimethylenediamine Complexes. III. <I>cis</I>-<I>trans</I> Isomeric Pairs of Diazido- and Dicyano-bis(trimethylenediamine)cobalt(III) Complexes
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概要
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<I>trans</I>-Diazido- and dicyano-bis(trimethylenediamine)cobalt(III) complexes have been prepared by the ligand substitution reactions of <I>trans</I>-dichlorohis(trimethylenediamine)cobalt(III) complexes in methanol. The corresponding <I>cis</I> isomers were obtained by similar reactions in aqueous solutions. The structural assignment of these isomeric pairs was made on the basis of electronic, infrared and nuclear magnetic resonance spectra.
- 公益社団法人 日本化学会の論文
著者
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Kawaguchi Shinichi
Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University
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Kawaguchi Hiroshi
Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University
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Kawaguchi Hiroshi
Department of Chemistry, Faculty of Science, Osaka City University
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Kawaguchi Shinichi
Department of Chemistry, Faculty of Science, Osaka City University
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